The invention provides a preparation method of a double-layer
graphene intercalation compound. The preparation method comprises the following steps: utilizing
iodine chloride as an intercalation agentto obtain a second-order
graphite intercalation compound, carrying out high-
temperature treatment on the second-order
graphite intercalation compound to decompose the
iodine chloride and then uses the generated gas to peel a
graphite sheet layer, thus obtaining double-layer high-quality
graphene material; by utilizing
ferric trichloride and the like as intercalation agents, applying a salt melting method to carry out intercalation on the double-layer high-quality
graphene material, thus obtaining the double-layer graphene intercalation compound. The preparation method provided by the invention has the beneficial effects that the double-layer graphene intercalation compound is obtained by utilizing controllable preparation of double-layer graphene, and with existence of the intercalation agents, the interlayer spacing is enlarged, and then migration of free carriers of a sheet layer also can be caused, so that different electrics, thermology and magnetics properties and the like are obtained; the graphene intercalation compound based on double-layer graphene overcomes the defect of too
large size of the traditional
graphite intercalation compound, and can be applied in the aspectsof manufacture of devices such as novel micro /
nanoelectronics, transparent electrodes and high-frequency transistors.