The invention discloses a preparation method of a high temperature-resistant composite polyimide dielectric material. According to the process, raw materials such as copper sulfate, dimethyl sulfone,ethanol, calcium carbonate, silicon dioxide, methyl hydroxybenzoate, polyimide, polyphenylene sulfide, polylactic acid fiber, benzoin dimethyl ether, lead magnesium niobate and polyvinyl alcohol are respectively subjected to the steps such as ultrasonic dispersion, centrifugal washing, drying, stepwise vacuum high temperature reaction, ice bath cooling, pressure banburying, extrusion granulation,molding and packaging to prepare the high temperature-resistant composite polyimide dielectric material. The prepared high temperature-resistant composite polyimide dielectric material is good in hightemperature resistance, anti-aging property and dielectric property, and can meet multiple user needs.