The invention discloses a preparation method of a
polystyrene-
acrylate core-shell composite
emulsion, belongs to the
emulsion preparation field, and solves the problems of adhesion resistance, poor
heat resistance and the like of a
thermoplastic polystyrene-
acrylate random
copolymer in the prior art. The preparation method is as follows: 1, weighing raw materials; 2, adding
distilled water into a reactor, heating up, adding a compound emulsifier, a pH buffer and then part of a mixed vinyl
monomer for emulsifying, adding part of an initiator, heating up to react until no
reflux exists to obtain a seed
emulsion; 3, continuing heating up, dripping off the rest of the mixed vinyl
monomer, synchronously adding part of the initiator, after the dripping of the part of the initiator, keeping warm to obtain a core structure emulsion; 4, dripping a mixed
acrylate monomer to the core structure emulsion, in the mixed monomer dripping process, adding part of the initiator, after dripping of the part of the initiator, adding the rest of the initiator, keeping warm, then cooling, adding
ammonia water, stirring, further cooling, and filtering. The preparation method is applied in the fields of wood veneering, interior decoration, textiles and the like.