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41results about How to "Long penetration time" patented technology

Preparation method of modified activated carbon fiber for adsorbing ultra-micro sulfur dioxide

The invention relates to a preparation method of modified activated carbon fiber for adsorbing ultra-micro sulfur dioxide, belonging to the technical field of gas adsorption and separation. The method comprises the following steps: taking viscose-based activated carbon fiber which is oxidized by dilute nitric acid as a matrix, and taking tris hydroxyl methyl aminomethan, alanine, serine and arginine as modifiers; and successfully preparing chemically modified activated carbon fibers in which the surfaces are modified by much amidogen through a hydro-thermal reaction under certain conditions. Compared with the prior art, the preparation method has the following advantages: (1) a micromolecule modifier is used for chemically modifying the surface to keep the structural advantage of the activated carbon fibers such as high specific surface and more micro pores so that the activated carbon fibers simultaneously have abundant micro-pore structures and high activity reaction surfaces to represent relatively longer penetrating time and larger saturation adsorption capacity; (2) the modifying method is temperate in condition, small in pollution, energy-saving and environment-friendly, and easy for scaled production; and (3) the modified absorbing capacity can be increased to that 1 g of the absorbent can absorb 40-60 mg of SO2, which is improved by 4-6 times compared with the absorbing capacity of the absorbent before the modification.
Owner:DALIAN UNIV OF TECH

Adsorbent with adsorption and oxidation synergistic effects on indoor toluene and preparation method and application of adsorbent

The invention relates to the technical field of indoor air purification and discloses an adsorbent with adsorption and oxidation synergistic effects on indoor toluene, and the loading capacity of potassium permanganate on an H-ZSM-5 molecular sieve is 0.05 to 1.The adsorbent has good oxidation performance and excellent absorption effect, toluene can be directly oxidized into benzoic acid, and the technical problem of vacant adsorption of indoor low-concentration toluene is solved. The invention further discloses a preparation method of the adsorbent with the adsorption and oxidation synergistic effects on the indoor toluene, H-ZSM-5 is used as an adsorption carrier, potassium permanganate is loaded on the adsorption carrier by virtue of dipping, and then drying is performed by a nitrogen blowing instrument. The preparation method has the advantages of simplicity, short consumed time and low cost, conforms to the concept of green chemistry and has a wide application prospect. The invention further relates to application of the adsorbent to indoor toluene treatment. An effective method is provided for indoor pollution gas treatment, and an important application value is realized in the aspect of life safety.
Owner:杭州朱庇特环境科技有限公司

Efficient enrichment and separation equipment for ultralow-concentration gas

The invention provides efficient enrichment and separation equipment for ultralow-concentration gas. The efficient enrichment and separation equipment comprises an air compressor, a mass flow meter, a solenoid valve, an infrared ray gas analyzer, a vacuum pump and an online collection system. The equipment has the advantages that a double-tower adsorption and desorption system is arranged; one tower is used for adsorption while the other tower is used for desorption; room-temperature and normal-pressure absorption, vacuum desorption and reaction conditions are easy to realize and the possibility of industrial large-scale production exists; the ultralow-concentration gas which is lower than 0.5% can be separated and purified and the problem that mine gas which is lower than 0.1% can not be used. The adsorption tower is internally provided with three adsorption pipelines which are connected in series so as to prolong the gas penetration time and improve the adsorption efficiency of an adsorbent; the adsorption tower is internally provided with a buffering region and is connected with a desorption tower through a pipeline so as to reduce the energy consumption of the vacuum pump in the switching work process, and improve the economic efficiency; a multi-grade concentration lifting device can meet different working conditions and can recycle low-concentration methane in product gas so as to further reduce the discharging of the methane.
Owner:CHINA UNIV OF MINING & TECH (BEIJING)

Preparation method of modified silicon gel absorbing agent used for protecting on-vehicle fuel batteries

InactiveCN101856606AEfficient removalGood ability to remove trace sulfur dioxideOther chemical processesFuel cell auxillariesFiberSilanes
The invention relates to a preparation method of a kind of modified silicon gel absorbing agent used for protecting on-vehicle fuel batteries, which belongs to the branch of the non-metallic inorganic material technology and is applied to the field of gas absorption and separation. The preparation method uses 3-aminopropyl triethoxysilane as amino modifying agents, uses tetraethoxy silane as silicon gel precursors, and prepares and obtains modified silicon gel with uniformly decorated amino groups in a porous silicon gel framework through adding a certain number of amino modifying agents in the gel forming stage. The absorbing agent can be used for removing a trace amount of sulfur dioxide in the air, so cathodic catalysts of on-vehicle proton exchange membrane fuel batteries are protected from the poisoning effect of the sulfur dioxide. Compared with the prior art, the invention has the following advantages that: (1) the obtained absorbing agent has better capability for absorbing the trace amount of sulfur dioxide than active carbon fiber, the effect is shown through longer penetrating time and larger saturation adsorption capacity, in addition, the absorbing agent still has good absorbing capability when the humidity is lower; and (2) the obtained absorbing agent has simple and convenient preparation method, the operation is easy, the condition is mild, and the effects of energy saving and environment protection can be obtained.
Owner:DALIAN UNIV OF TECH

Monolithic composite porous carbon adsorption material for separating methane and nitrogen, and preparation method thereof

The invention provides a monolithic composite porous carbon adsorption material for separating methane and nitrogen, and a preparation method thereof, wherein the monolithic composite porous carbon adsorption material is a macropore-mesopore-micropore tandem composite porous carbon, the pore size range of the micropores is 0.50-1.20 nm, and the surface has polar sites and can be regulated. According to the present invention, the monolithic composite porous carbon adsorption material has a dynamic methane adsorption amount of up to 0.79 mmol.g<-1> at a normal temperature under a normal pressure, has methane/nitrogen separation selectivity of 16, has good industrial application prospect, and further has a multi-level pore channel structure, wherein the macropores and the mesopores facilitatecan easily achieve the diffusion of methane, and the micropores can easily increase the adsorption amount of methane; the method for regulating the surface chemical property and the pore structure ofthe adsorption materials is simple and easy to control, and provides the reference for the design of adsorbents for difficultly-separated mixed gases; and the adsorption material of the invention hasgood application effect in the field of methane and nitrogen separation, and provides the technical support for the concentration and purification of unconventional natural gases such as coalbed methane and the like.
Owner:DALIAN UNIV OF TECH

Refrigeration assisted adsorption type VOCs (volatile organic compounds) recovery device and recovery method

A refrigeration assisted adsorption type VOCs (volatile organic compounds) recovery device and recovery method belongs to the fields of energy utilization, resource recovery, environmental protection and the like. The device comprises a coarse filtration unit, a cooling unit, an absorption device, a fan, a vacuum pump and a branch diversion channel which are sequentially connected. The method comprises steps of coarse filtration, cooling for vapour removal and gas mixture cooling, adsorption, heating assisted vacuum desorption, cooling capacity recovery, exhausting and the like sequentially. The cooling unit comprises an evaporator, a compressor, a forced air cooling condenser, a liquid storage tank, a throttle valve and the like. The cooling unit is used for removing vapour in a gas mixture, and reducing the temperature of the gas mixture, so as to remarkably improve the subsequent absorption effect and prolong the service cycle of the absorption device. The recovery device is high in recovery efficiency, relatively low in cost, simple in structure, long in service life, and easy to control and operate, and is particularly suitable for recovery processing of low concentration VOCs, which are not suitable for condensation methods, in chemical engineering, automobile industry and other fields.
Owner:BEIJING UNIV OF TECH +1

Method for preparing absorbing agent for medium-temperature gas desulfurization

The invention discloses a method for preparing an absorbing agent for medium-temperature gas desulfurization. The method comprises that an isometrical ferric nitrate solution is soaked in a Gamma-Al203 carrier isometrically, vacuum impregnation and ultrasonic wave impregnation are performed simultaneously, and the absorbing agent for medium-temperature gas desulfurization with an active componentof ferric oxide is obtained after vacuum drying and high-temperature roasting. During the preparation process of the absorbing agent for medium-temperature gas desulfurization, by the aid of ultrasonic and vacuum synergy effects, the specific surface area of the carrier is improved, the active component is loaded on the carrier uniformly simultaneously, a hole structure of the carrier is improved, component load and drying are completed under ultrasonic and vacuum action, the active component of the prepared absorbing agent is distributed uniformly on the surface of the carrier, the utilization rate of the active component is high, the breakthrough sulfur capacity is large, and the breakthrough time is long.
Owner:TAIYUAN UNIV OF TECH

Composite molecular sieve, desulfurization adsorbent and preparation method and application thereof

The invention provides a composite molecular sieve, a desulfurization adsorbent as well as a preparation method and application thereof. The preparation method of the composite molecular sieve comprises the following steps: adding a template agent for preparing a mesoporous molecular sieve into an alkaline solution, and stirring to obtain a clear solution; adding a metal zinc in-situ modified silicon-aluminum molecular sieve into the clear solution, and stirring to obtain a turbid liquid; adding a silicon source into the turbid liquid for stirring reaction, and filtering, drying and roasting after reaction to obtain the composite molecular sieve. The desulfurization adsorbent is prepared from the following raw materials in parts by weight: 30-70 parts of a composite molecular sieve, 1-10 parts of an IA group and / or IIA group metal oxygen-containing compound precursor and 30-60 parts of a binder. The desulfurization adsorbent disclosed by the invention is high in adsorption capacity, good in selectivity, high in desulfurization precision, capable of being recycled and long in service life; and C5 oil desulfurized by the desulfurization adsorbent can be directly used as a raw material for high-value utilization.
Owner:CHINA UNIV OF PETROLEUM (BEIJING)

Preparation method and application of stacking-coral-like biomass-charcoal-based catalyst

The invention discloses a preparation method of a stacking-coral-like biomass-charcoal-based catalyst. The preparation method comprises the following steps: cleaning and crushing a biomass raw material, and conducting carbonizing under the protection of inert gas; performing grinding, then carrying out washing with water to remove impurities on the surface of a carbonized material, and then conducting drying to obtain a biomass-charcoal-based carrier; mixing the biomass-charcoal-based carrier, a nitrate solution and nitric acid in a reaction kettle, and then performing a hydrothermal reaction to prepare a biomass-charcoal-based catalyst precursor; and roasting the biomass-charcoal-based catalyst precursor in an inert atmosphere to obtain the stacking-coral-like biomass-charcoal-based catalyst. Compared with a traditional impregnation method, the catalyst prepared by the method disclosed by the invention has the advantages that an active component has a unique morphological structure, so the active component is exposed more sufficiently, and the catalyst can adapt to different flue gas atmospheres to remove different sulfur-containing gases; the activity of the catalyst is higher, penetration time is longer, and the sulfur capacity of the catalyst is larger; and raw materials are wide in source, cost is low, and the method is suitable for industrial production and market popularization and application.
Owner:KUNMING UNIV OF SCI & TECH

Perfluoroisobutyronitrile/carbon dioxide recovered insulating gas adsorption, purification and recycling method

The invention relates to a perfluoroisobutyronitrile/carbon dioxide recovered insulating gas adsorption, purification and recycling method, which comprises the following steps: (1) carrying out adsorption and purification: introducing recovered insulating gas into a fixed bed adsorption column filled with an adsorbent, and removing most organic impurities, water and HF; and (2) reproportioning the gas: measuring the volume ratio of the perfluoroisobutyronitrile/carbon dioxide in the adsorbed mixed gas, and directly recycling after reproportioning the volume ratio. The adsorbent adopted by the invention can effectively adsorb impurities in the perfluoroisobutyronitrile recovery gas, the adsorption rate of organic impurities reaches 99.1%, and meanwhile, the adsorbent also has a very good removal effect on moisture and HF. The recovered insulating gas subjected to primary adsorption can meet the lowest impurity requirement, the perfluoroisobutyronitrile and carbon dioxide do not need to be purified and blended respectively, only the adsorbed gas needs to be supplemented to the required perfluoroisobutyronitrile/carbon dioxide ratio, the method is simple and practical, and the recycling cost is greatly reduced.
Owner:CHEM & CHEM ENG GUANGDONG LAB +1

Refrigeration-assisted adsorption type vocs recovery device and recovery method

A refrigeration assisted adsorption type VOCs (volatile organic compounds) recovery device and recovery method belongs to the fields of energy utilization, resource recovery, environmental protection and the like. The device comprises a coarse filtration unit, a cooling unit, an absorption device, a fan, a vacuum pump and a branch diversion channel which are sequentially connected. The method comprises steps of coarse filtration, cooling for vapour removal and gas mixture cooling, adsorption, heating assisted vacuum desorption, cooling capacity recovery, exhausting and the like sequentially. The cooling unit comprises an evaporator, a compressor, a forced air cooling condenser, a liquid storage tank, a throttle valve and the like. The cooling unit is used for removing vapour in a gas mixture, and reducing the temperature of the gas mixture, so as to remarkably improve the subsequent absorption effect and prolong the service cycle of the absorption device. The recovery device is high in recovery efficiency, relatively low in cost, simple in structure, long in service life, and easy to control and operate, and is particularly suitable for recovery processing of low concentration VOCs, which are not suitable for condensation methods, in chemical engineering, automobile industry and other fields.
Owner:BEIJING UNIV OF TECH +1

A molecular sieve ceramic membrane material for olefin purification and its preparation and application

The invention relates to a molecular sieve ceramic membrane material for olefin purification as well as a preparation method and application of the molecular sieve ceramic membrane material. In the molecular sieve ceramic membrane material, the particle sizes of molecular sieve particles supported on the surface of the ceramic material are 0.1-3 [mu]m, and the thickness of a molecular sieve layeris 3-5 [mu]m; during preparation, ceramic material pretreatment, molecular sieve seed crystal pre-coating and sealed crystallization are sequentially carried out; and the molecular sieve ceramic membrane material is used for removing a polar oxygenated compound in a gaseous olefin flow to be 1ppm or below. Compared with the prior art, the molecular sieve ceramic membrane material prepared by the preparation method of the invention has the molecular sieve layer with higher mechanical strength, larger specific surface area and uniform thickness, in addition, the molecular sieve layer has no longitudinal or horizontal cracks, has no air pores in the surface and is high in bonding strength and not easy to fall off; and when the polar oxygenated compound in the olefin flow is adsorbed, the purification depth is 1ppm or smaller, so that not only is the mass transfer resistance lower, but also the energy consumption is lower, and the regeneration capacity is high.
Owner:SHANGHAI LVQIANG NEW MATERIALS CO LTD +1

Water-based antirust paint and preparation method thereof

The invention discloses waterborne antirust paint and a preparation method thereof. The waterborne antirust paint is prepared from, by mass, 10-25 parts of waterborne acrylic acid modified epoxy ester, 0.6-1.2 parts of neutralizer, 20-30 parts of deionized water, 0.5-1.5 parts of dispersing agents, 0.2-0.5 part of defoaming agent, 14-18 parts of iron oxide red, 2-4 parts of mica powder, 6-10 parts of modified zinc phosphate, 10-14 parts of precipitated barium sulphate, 1-2 parts of propylene glycol, 10-15 parts of styrene-acrylic emulsion, 0.5-1.0 part of coalescing agent, 0.5-1.0 part of waterborne flush rust prevention agent, 0.5-1.5 parts of thickening agents and 0.2-0.5 part of mildew prevention agent. The waterborne antirust paint is high in film hardness, good in adhesive force and excellent in corrosion-resistant performance and mechanical performance, dryness and initial water resistance of paint films are remarkably improved due to the addition of styrene-acrylic emulsion, and the flush rust restraining performance of paint films is improved due to the addition of the waterborne flush rust prevention agent. Water serves as the diluent for the waterborne antirust paint, VOC emission in production and construction projects is greatly reduced, and the waterborne antirust paint is safe, environmentally friendly and capable of being widely used for paint coating on the aspects of steel structures, pipelines, automobile parts and the like.
Owner:西北永新涂料有限公司
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