The invention relates to a
copper alloy surface micro-
etching solution and a preparation method thereof, and belongs to the technical field of micro-
etching solutions. The
copper alloy surface micro-
etching liquid is prepared by taking a self-made supported phosphotungstic heteropolyacid catalyst, glacial
acetic acid, a
hydrogen peroxide solution, a buffer agent, a stabilizer and a
corrosion inhibitor as raw materials, and the
copper alloy surface micro-etching liquid is prepared by the following steps: firstly, synthesizing
peracetic acid with higher oxidability by using the catalyst,
hydrogen peroxide and glacial
acetic acid; according to the micro-etching liquid, the
copper alloy surface is etched under the weak acidic condition, the
conductivity of the micro-etching liquid is further reduced, the purpose of inhibiting the
galvanic effect of the
copper alloy surface is achieved, in addition, due to the existence of a large number of acetate ions, the content of
metal ions in the micro-etching liquid is very low, a pH buffer
system exists, and the
corrosion resistance of the
copper alloy surface is improved. The influence of the overall oxidability of the micro-etching liquid along with the change of the reaction time is small, the etching effect is uniform, the concentration of a
single component can be reduced through a
hydrogen peroxide /
peracetic acid compound system, and damage to a base material due to the too high
single component is avoided.