The method comprises the following steps:
drying, crushing and screening
deep sea manganese nodules, uniformly mixing the screened
deep sea manganese nodules with a flux, heating to 200 DEG C in a tubular furnace under the protection of
inert gas,
roasting at a constant temperature, heating to 290 DEG C,
roasting at a constant temperature, heating to 640 DEG C,
roasting at a constant temperature, and naturally cooling to
room temperature after roasting, thereby obtaining the
manganese. And adding deionized water to leach manganese
sulfate from the roasted sample at
room temperature, filtering and separating, carrying out graded purification and
impurity removal on the filtrate, adding
ammonium bicarbonate to convert manganese
sulfate into manganese
carbonate, filtering, washing with deionized water, and calcining to obtain manganous-manganic
oxide. The method comprises the following steps: forming a
reducing atmosphere by using a flux under the protection of
inert gas, reducing high-valence manganese into low-valence manganese by fully utilizing a manganese source in the deep-sea
manganese nodule, carrying out
sulfation reaction by using the low-valence manganese, and immersing the formed soluble manganese
sulfate in deionized water, thereby efficiently extracting manganese from the deep-sea
manganese nodule.