The invention relates to a
tail gas
recovery process for producing insoluble
sulfur by a high-temperature liquid
sulfur atomization direct method, which comprises the following steps: S1, carrying out
quenching granulation on high-temperature
tail gas through a
quenching tower, atomizing liquid
sulfur into liquid drops with the particle size of 50-200mu m by using an atomizing
nozzle, directly contacting the liquid sulfur with the high-temperature
tail gas, and quickly condensing into spherical sulfur particles, and controlling the
cooling rate to be 103-104 DEG C / s through low-temperature circulating oil or
liquid carbon dioxide, inhibiting
particle aggregation, and obtaining the monodisperse sulfur microspheres. Modified
white oil or dimethyl
silicone oil is adopted as an absorbent, and spraying of an alkaline solution is combined, so that deep purification of harmful substances such as sulfur steam,
sulfur dioxide and
hydrogen sulfide is realized, and the monodisperse sulfur microspheres are obtained. The tail gas
recovery rate reaches up to 95% or above, meanwhile, the recovered sulfur particles and byproducts can be recycled, the
resource utilization rate is increased, particle size regulation and morphology optimization of the sulfur particles are synchronously achieved in the tail gas
recovery process, and spherical or regular-shaped sulfur particles meeting the high-end market requirement can be produced.