The invention discloses a mud cake hardening enhancer for drilling fluid. The enhancer is characterized by composing polysiloxane, a mud cake hardener, a low molecular weight polymer, a film former and an organic chelating agent; the mass ratio of the mud cake hardener, the low molecular weight polymer, the film former and the organic chelating agent is 30-45:35-50:5-12:8-15:2-8. By adding the mudcake hardening enhancer to the drilling fluid and completion fluid, the properties of a drilling fluid mud cake can be effectively changed, the quality of the drilling fluid mud cake can be improved,the thickness of the mud cake can be reduced, the thin and tough mud cake can be formed, the strength of the mud cake can be increased, thereby improving the interface cementation strength during well cementing, the physical combination of a cementing interface is transformed into chemical affinity, thereby improving the interface cementation quality between the mud cake and a cement ring and a casing and the cement ring, the interface cementation permeability rate is reduced, the cementing quality rate is improved, the service life of oil and gas wells is prolonged, and a crude oil recoveryratio is correspondingly improved.