The invention discloses a method for preparing biodegradable rigid
polyurethane foam with
liquefaction products of bamboo waste, which comprises the following steps: 1
mass portion of crude glycerin /
polyethylene glycol liquefying
solvent and 0.02-0.04
mass portion of concentrated
sulfuric acid are added into a reaction vessel, heated till the temperature reaches 120-180 DEG C after a
reflux condensation tube is connected to the reaction vessel; 0.2-0.5
mass portion of crushed and dried bamboo waste is added, reacted for 90-180min with stirring, taken out and cooled and neutralized by MgO tillbeing neutral; 1 mass portion of
liquefaction products of bamboo waste, 0.02-0.08 portion of a
dibutyl tin dilaurate / triethylene
diamine mixed catalyst, 0.02-0.06 portion of
silicone oil, 0.02-0.1 portion of water and 0.1-0.15 portion of
fire retardant are added into a container, premixed for 20-30s when stirred at 2,000r / min, added with sufficient PAPI with the
molar ratio between isocyanato-NCOin PAPI and hydroxyl group-OH in bamboo waste
liquefaction products being 0.6-1.2, stirred for 10s-15s at 1,000r / min, put into a mould, foamed with standing at
room temperature, placed for slaking and mould separating at
room temperature for 24h-72h after reaction. The method fully utilizes resources, reduces liquefaction cost, and has a mild
reaction temperature and stable liquefaction products;the performance of obtained foam meets the
national standard and biodegradability.