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42results about How to "Little impact on physical and mechanical properties" patented technology

Halogen-free expansion flame retardant and flame-retardant polypropylene composite material

The invention discloses a halogen-free expansive flame retardant and a composite material of flame retardant polypropylene, relating to a composite material of expansive flame retardant and polypropylene, which settles the problem that the prior halogen-free expansive flame retardant is unsuitable for commercial production due to low flame retardant efficiency, large addition quantity, bad thermostability and reduced polymer performance after added, the polypropylene is unsuitable for commercial production, and the application range in the composite material is greatly reduced. The halogen-free expansive flame retardant comprises triazine carbon-formation foaming agent, ammonium polyphosphate and halogen-free flame retardant synergistic agent. The composite material of flame retardant polypropylene comprises thermoplastic resin and halogen-free expansive flame retardant, and processing aid and / or anti-dripping agent as well. The composite material of flame retardant polypropylene has the advantages of high flame retardant efficiency, high oxygen index, non-halogen, low smoke, low mammalian toxicity and excellent processing properties since the halogen-free expansive flame retardant has the advantages of high flame retardant efficiency, less addition quantity, less influence to the physical mechanical property of the composite material, suitability for commercial production and wide application range.
Owner:NORTHEAST FORESTRY UNIVERSITY

Flame retardant soft foam polyether polyol and synthesis method thereof

ActiveCN102875791AGood durability of flame retardant performanceExcellent physical performance indexHigh oxygenBase metal
The invention relates to a flame retardant soft foam polyether polyol and a synthesis method thereof. The technical scheme is to provide the flame retardant soft foam polyether polyol which is good in flame retardant property, safe and non-toxic, simple in preparation process and low in cost and the synthesis method of the flame retardant soft foam polyether polyol. The synthesis method disclosed by the invention comprises the following steps of enabling melamine-formaldehyde condensation compound to react with amine compounds, polymerizing the reaction product with an acid compound to obtain a polyether initiator, further polymerizing the polyether initiator with oxyalkylene with the action of a base metal catalyst so as to obtain the flame retardant polyether polyol. The flame retardant polyether polyol synthesized by the method has the advantages of light colour, low viscosity and good material flowability, and can be widely used for preparing the flame retardant polyether soft foam. The flame retardant soft polyether foam plastic products foamed and prepared by the flame retardant polyether polyol disclosed by the invention have the characteristics of good flame retardant effect, high oxygen index, good foam uniformity, good size stability and high mechanical strength.
Owner:SHANDONG BLUSR DONGDA CHEM

Flame-retardant and wear-proof corrugated case

The invention discloses a flame-retardant and wear-proof corrugated case. The flame-retardant and wear-proof corrugated case comprises a case body composed of a corrugated paperboard. The paperboard sequentially comprises surface paper, corrugated paper and inner paper from outside to inside, and the surface paper, the corrugated paper and the inner paper are boned through oxidized starch, a vapor phase inhibitor is added into the oxidized starch, the surfaces of the surface paper and the inner paper are coated with a flame-retardant and wear-proof coating, and the coating is prepared from, by weight, 30-40 parts of phenolic resin, 10-15 parts of nanometer Sb2O3-Al(OH)3, 10-20 parts of nanometer wear-proof powder, 1-3 parts of a reactive diluent, 0.5-2 parts of an antifoaming agent, 2-5 parts of a penetrating agent, 0.5-1 part of an antioxidant, 10-20 parts of an organic solvent and 10-20 parts of a curing agent. According to the flame-retardant and wear-proof corrugated case, as cashew-nut-shell-oil-or-tripolycyanamide-modified phenolic resin is applied to the surface of the paper case, the quite-high wear-proof performance and the quite-high mechanical performance are achieved; meanwhile, the wear-proof nanometer powder is added into the coating, the wear-proof capacity of the surface of the paper case is enhanced, and a nanometer aluminum hydroxide is used as a flame retardant to achieve the aim of reducing the using amount and improving the flame-retardant performance.
Owner:CHUZHOU CIGARETTE MATERIALS FACTORY

Epoxy resin reaction-type microcapsule fire retardant and preparation method thereof

InactiveCN102585292AImprove temperature and humidity resistanceImprove flame retardant performanceSolubilityEpoxy
The invention belongs to the field of polymer flame retardation and discloses an epoxy resin reaction-type microcapsule fire retardant and a preparation method thereof. The epoxy resin reaction-type microcapsule fire retardant is characterized in that at least one phosphorus-containing fire retardant is utilized as a capsule core; a product of a reaction of at least one curing agent, an epoxy resin and triglycidyl isocyanurate is utilized as a capsule material; a mass ratio of the capsule material to the capsule core is (0.05 to 0.4): 1; and a mass ratio of the epoxy resin to the triglycidyl isocyanurate is (0 to 6): 1. The preparation method provided by the invention comprises the following steps of dispersing the at least one phosphorus-containing fire retardant in at least one solvent,heating, adding a triglycidyl isocyanurate solution and an epoxy resin solution into the heated solution, stirring for a reaction for 10 to 30 minutes, dropwisely adding a curing agent solution into the reaction system, carrying out a reaction process for 1 to 2 hours, heating to a temperature of 70 to 78 DEG C, carrying out a reaction process for 2 to 12 hours, cooling, filtering, washing and drying to obtain the epoxy resin reaction-type microcapsule fire retardant. The epoxy resin reaction-type microcapsule fire retardant has uniform granularity, good liquidity, low water-solubility and good polymer compatibility. Through utilization of the epoxy resin reaction-type microcapsule fire retardant, good flame resistance, good water tolerance and good mechanical properties are obtained.
Owner:GUANGZHOU CHEM CO LTD CHINESE ACADEMY OF SCI

Compound type uvioresistant antibacterial agent and preparation method thereof

The invention discloses a compound type uvioresistant antibacterial agent and a preparation method thereof. The preparation method for the compound type uvioresistant antibacterial agent comprises the following steps of: firstly, coarsening talc powder by adopting fluohydric acid; secondly, sensitizing the talc powder after coarsening; and finally, performing silver deposition reaction on the talc powder after sensitizing. Metallic state silver of which the weight is 5 to 10 percent of that of the talc powder and the thickness is 50 to 100 nanometers is deposited and coated on the surface of the talc powder. By using the ultraviolet shielding, absorbing and bacteriostatic functions of nano-state metallic silver, the preparation method prepares the compound type uvioresistant antibacterialagent which simultaneous has uvioresistant and antibacterial functions by depositing the nano silver on the surface of the talc powder. The compound type uvioresistant antibacterial agent has the advantages of simplicity, practicability, high uvioresistant antibacterial efficiency, wide application range, large-scale production and the like. The compound type uvioresistant antibacterial agent provided by the invention can be widely applied to the industries of textiles, plastics, coatings and the like, and has good economical and social benefits.
Owner:ZHEJIANG SCI-TECH UNIV

Water-expandable flexible flame-retardant foam plastic and preparation method thereof

The invention relates to water-expandable flexible flame-retardant foam plastic. The water-expandable flexible flame-retardant foam plastic is prepared from the following raw materials in parts by weight: 40-60 parts of a polyester polyol and/or a polyether polyol, 5-10 parts of s graft copolymer of polyvinyl alcohol/an isocyanate group silane coupling agent, 50-90 parts of a polyisocyanate, 1-5 parts of an opening agent, 0.2-3 parts of a foam stabilizer, 5-20 parts of a compound foaming agent, 10-30 parts of a modified flame retardant and 0.2-1 part of a catalyst. The invention simultaneouslyfurther provides a preparation method of the water-expandable flexible flame-retardant foam plastic. According to the prepared water-expandable flexible flame-retardant foam plastic, the graft copolymer of the polyvinyl alcohol/the silane coupling agent is introduced on a polyurethane foam skeleton, unexpectedly it is found that the water absorption capacity and the water retaining capacity of obtained polyurethane foam are enhanced, thus the prepared foam plastic has better water absorption expansion rate and rebound resilience, and the application field of polyester foam is widened; and theflame retardant reacts to a skeleton molecule, intrinsic flame-retardant foam plastic is formed, migration and precipitation of the flame retardant are avoided, so that the flame retardant effect lasts longer, and the effect on the physical and mechanical properties of a material is less.
Owner:中电保力(北京)科技有限公司

Tin antimony oxide dispersion liquid for improving fiber conduction performance, preparation method of tin antimony oxide dispersion liquid and preparation method of conductive regeneration cellulose fiber

The invention discloses tin antimony oxide dispersion liquid for improving the fiber conduction performance, a preparation method of the tin antimony oxide dispersion liquid and a preparation method of conductive regeneration cellulose fiber. The dispersion liquid is prepared by mixing ammonium polycarboxylate solution, soft water, ATO powder and sodium hexametaphosphate according to the weight ratio of (4 to 8):(2 to 6):(0.5 to 3):(0.1 to 0.5); the pH value of the dispersion liquid is 8 to 12. The dispersion liquid is added into prepared spinning viscose according to the addition quantity that the ATO powder in the dispersion liquid accounts for 3 to 10 weight percent of the methylcellulose in the spinning viscose; after the uniform mixing, the blending viscose raw liquid is obtained. Theblending viscose raw liquid is subjected to coagulating bath spinning shaping; then, refining and drying are performed to obtain the conduction regenerated cellulose fiber. The tin antimony oxide dispersion liquid is used for modified preparation of the conductive fiber; the addition quantity of the conductive powder is low; the conductive body and the cellulose are tightly combined; falling cannot easily occur in the subsequent use and processing process.
Owner:赛得利(盐城)纤维有限公司

Compound type uvioresistant antibacterial agent and preparation method thereof

The invention discloses a compound type uvioresistant antibacterial agent and a preparation method thereof. The preparation method for the compound type uvioresistant antibacterial agent comprises the following steps of: firstly, coarsening talc powder by adopting fluohydric acid; secondly, sensitizing the talc powder after coarsening; and finally, performing silver deposition reaction on the talc powder after sensitizing. Metallic state silver of which the weight is 5 to 10 percent of that of the talc powder and the thickness is 50 to 100 nanometers is deposited and coated on the surface of the talc powder. By using the ultraviolet shielding, absorbing and bacteriostatic functions of nano-state metallic silver, the preparation method prepares the compound type uvioresistant antibacterialagent which simultaneous has uvioresistant and antibacterial functions by depositing the nano silver on the surface of the talc powder. The compound type uvioresistant antibacterial agent has the advantages of simplicity, practicability, high uvioresistant antibacterial efficiency, wide application range, large-scale production and the like. The compound type uvioresistant antibacterial agent provided by the invention can be widely applied to the industries of textiles, plastics, coatings and the like, and has good economical and social benefits.
Owner:ZHEJIANG SCI-TECH UNIV

A kind of phosphorus-silicon composite flame retardant and its preparation method and application

ActiveCN104448830BExcellent heat insulation and smoke suppressionEasy to processGroup 5/15 element organic compoundsPolymer scienceThermal insulation
The invention discloses a phosphorus-silicon composite flame retardant as well as a preparation method and application thereof. The phosphorus-silicon composite flame retardant is a cage-like tetraphenyl trisilicate phosphorus silsesquioxane shown in the description, and the flame retardant is prepared according to the following steps: firstly hydrolyzing POSS to chipping POSS under the action of an organic alkali, and then carrying out reaction of the chipping POSS with metaphosphoric acid. Experiments show that the phosphorus-silicon composite flame retardant provided by the invention gives full play to the advantages of a silicon flame retardant and a phosphorus flame retardant, compensates defects of the silicon flame retardant and the phosphorus flame retardant, has significant synergistic flame retardance and complementarity, and excellent thermal insulation, smoke suppression and oxygen supply cutoff functions, also has the functions of protecting the environment, safety and preventing molten drop, can be directly used for preparing silicone rubber, can not only improve the flame retardance of the silicone rubber, but also perfect the thermal insulation, smoke suppression and mechanical properties of the silicone rubber, and the phosphorus-silicon composite flame retardant has the advantages of being low in preparation and application costs, easy to realize large-scale industrialized production, and the like.
Owner:SHANGHAI UNIV OF ENG SCI
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