The invention relates to an application method of a double-layer continuous casting tundish covering agent, which belongs to the technical field of the continuous casting. The invention relates to a comprehensive using method of two covering agents when the low carbon and ultra-low carbon steel grades which have high requirements on the steel cleanliness are casted, bottom slag begins to be added after a large ladle is casted and is sufficiently added after the liquid lever of molten steel is positioned, and five minutes later, top slag is added at the temperature measuring and sampling location according to proportions; the percentages by weight between the bottom slag and the top slag are that: the top slag is 75-85 percent and the bottom slag is 15-25 percent. The invention has the advantages that the bottom slag keeps the characteristic that the high-basicity covering agent has strong absorbing and intermingling capability, at the same time, the second oxidation of the molten steel can be prevented and the carbolic content in the molten steel can be reduced; the top slag can cover the molten steel by taking a loose and porous shape, the incrusting phenomenon of the covering agent at the temperature measuring and sampling location can be improved obviously, the normal temperature measuring and sampling can be carried out and the invalidation loss caused by the incrusting of a temperature measuring head and a sampler can be reduced; the operation is simple, the covering agent of the common steel grades can be used as the bottom slag and the shell-broken operation is not carried out any more; the operational condition pollution caused by carbonizing rice huskes can be avoided.