The invention discloses an A-site
ion-doped
sodium bismuth titanate based lead-free piezoelectric
ceramic and a preparation method thereof. The
sodium bismuth titanate based lead-free piezoelectric
ceramic has the following
chemical formula: 0.852{Bi<0.5>[Na<1-x>Li<x>]<0.5>}TiO<3>-0.110(Bi<0.5>K<0.5>)TiO<3>-0.038BaTiO<3>, and the
chemical formula is denoted as BNKBT-xLi, wherein 0.12<=x<=0.13. Thepreparation method comprises the following steps: respectively preparing
sodium carbonate,
potassium carbonate,
bismuth trioxide,
titanium dioxide,
lithium carbonate and
barium carbonate according tothe
chemical formula, performing ball milling, performing
drying, performing pre-synthesis on the mixed raw materials at 800-900 DEG C, performing
granulation, performing molding, performing debinding, and performing
sintering at 1100-1140 DEG C to obtain the high-performance A-site
ion-doped modified
sodium bismuth titanate based lead-free piezoelectric
ceramic. The method provided by the invention not only optimizes
sintering temperature, reduces volatilization of an
alkali metal, but also improves strain performance, wherein the maximum strain S is 0.42%, the inverse
piezoelectric coefficient d33* is 760 pm / V, and the
saturation polarization intensity Ps is 34-38 [mu]C / cm<2>.