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42 results about "Saturation polarization" patented technology

The saturation is shown to originate from an unusual and strong electron-ion correlation that leads to cancellation between electronic and ionic polarizations. Our results shed new insight on the polarization properties, and reveal the existence of a fundamental limit to the strain-induced polarization enhancement.

Sodium bismuth titanate-based ferroelectric ceramic as well as preparation method and application thereof

The invention relates to a sodium bismuth titanate-based ferroelectric ceramic as well as a preparation method and the application thereof. A general chemical formula of the sodium bismuth titanate-based ferroelectric ceramic is (1-x)[0.9(0.94Na0.5Bi0.5TiO3-0.06BaTiO3)-0.1NaNbO3]-xZn, wherein x in the formula is greater than or equal to 0 and less than or equal to 0.01. The preparation method comprises the following steps: firstly, preparing all raw material components according to the stoichiometric ratio, then uniformly mixing all the raw material components and carrying out pre-sintering and grinding in sequence to obtain a ground powder body; secondly, carrying out granulating to obtain a granulated powder body; thirdly, carrying out dry pressing and cold isostatic pressing to obtain a densified ceramic green body, carrying out adhesive removal on the densified ceramic green body, and then sintering to obtain the sodium bismuth titanate-based ferroelectric ceramic. According to the preparation method disclosed by the invention, by doping zinc in the sodium bismuth titanate-based ferroelectric ceramic, the breakdown strength and a saturation polarization value of the sodium bismuth titanate-based ferroelectric ceramic are improved, the energy storage density and the stability are improved, leakage current is reduced, growth orientation of crystals is benefited as well as development and application of high-power and high-capacity storage capacitors are facilitated.
Owner:INNER MONGOLIA UNIV OF SCI & TECH

Organic molecular ferroelectric crystal di-n-butylamine difluoromonochloroacetate, preparation method therefor and use of organic molecular ferroelectric crystal di-n-butylamine difluoromonochloroacetate

The invention relates to an organic molecular ferroelectric crystal di-n-butylamine difluoromonochloroacetate, a preparation method therefor and use of the organic molecular ferroelectric crystal di-n-butylamine difluoromonochloroacetate. Proven by tests on electric hysteresis loop of the organic molecular ferroelectric crystal material, i.e., di-n-butylamine difluoromonochloroacetate through a Sawyer-Tower circuit, the material shows good ferroelectric properties in a ferroelectric phase and has relatively high saturation polarization strength reaching 3.9[mu]c/cm<2> and moderate coercive field about 12.4kV/cm. Proven by variable temperature nonlinear tests, the material does not have obvious second-order nonlinear frequency-doubled signals in a paraelectric phase, obvious second-order nonlinear frequency-doubled signals appear when the temperature is cooled to Curie temperature (243K), the strength value of the nonlinear signals is saturated along with decrease of temperature, excellent nonlinear on/off performance is shown in an entire test temperature range, the on/off ratio reaches 28, and the repeatability is relatively good. The reaction is simple, and the conditions are moderate.
Owner:FUJIAN INST OF RES ON THE STRUCTURE OF MATTER CHINESE ACAD OF SCI

High-polarization-intensity bismuth ferrite thick film material system and medium and low temperature preparation method

The invention provides a high-polarization-intensity bismuth ferrite thick film material system and a medium and low temperature preparation method. The high-polarization-intensity bismuth ferrite thick film material system comprises a base body, a buffer layer, a bottom electrode, a bismuth ferrite dielectric layer and a top electrode. Semiconductor monocrystalline acts as the base body, the buffer layer acts as a metal or metal oxide thin layer, and the bottom electrode acts as an inert metal thin layer. According to the preparation technology, crystallization temperature of the material system is relatively low (<=500 DEG C) so that application of a large-area silicon integrated circuit is facilitated; and volatilization of elements in the material system is greatly reduced by low crystallization temperature so that generation of the defect of oxygen vacancy of the material can be avoided and film material with excellent performance can be acquired, saturation polarization intensity can be 130muC/cm2, and external voltage which can be withstood is not less than 200V. The technological process and equipment operation are easy, the used raw material is sold on the market, cost is relatively low and device integration is easy so that the method is suitable for industrial popularization and production.
Owner:欧阳俊

Barium titanate/lanthanum nickelate ferroelectric superlattice film material and preparation method thereof

The invention aims to provide a barium titanate/lanthanum nickelate ferroelectric superlattice film material and a preparation method thereof. The material is composed of a ferroelectric oxide material barium titanate and a metal conductive oxide material lanthanum nickelate which grow periodically. The barium titanate/lanthanum nickelate ferroelectric superlattice film material has the advantagesthat the dielectric constant is increased by 11-90% compared with that of a pure barium titanate film; the barium titanate film has good ferroelectric polarization performance, the remnant polarization intensity of the barium titanate film reaches 13.1 mu C/cm<2>, the saturation polarization intensity of the barium titanate film reaches 34.6 mu C/cm<2>, and compared with a pure barium titanate film, the remnant polarization intensity of the barium titanate film is improved by 140%, and the saturation polarization intensity of the barium titanate film is improved by 58%. According to the preparation method of the material, lanthanum nickelate and barium titanate are alternately grown on a single crystal substrate by using a pulse laser deposition method, and the period thickness of superlattices is accurately regulated and controlled by controlling the time of laser bombarding different target materials. The ferroelectric superlattice material has wide application prospects in ferroelectric memories, sensors, actuators and other integrated ferroelectric devices.
Owner:SHENYANG POLYTECHNIC UNIV

Phenanthroline copper malonate ferroelectric electric functional material and preparation method thereof

The invention discloses a phenanthroline copper malonate ferroelectric functional material and a preparation method thereof. The ferroelectric functional material has a molecular formula of [Cu3(C12H8N2)3(H2O)2(C3H2O4)3].11H2O, is blue powder of which the purity is not lower than 99%, and has a C2 polarity point group structure. The ferroelectric characteristic parameters of the ferroelectric functional material are as follows: the remanent polarization strength 2Pr is equal to 0.09 muC.cm<-2>, the coercive electric field 2Ec is equal to 1.40kv.cm<-1>, and the saturation polarization strength Ps is equal to 0.39 muC.cm<-2>; and the cell parameter of the powder of the ferroelectric functional material is as follows: the saturation polarization strength of the ferroelectric functional material is 1.56 times that of Rochelle salt, so that the ferroelectric functional material is a new ferroelectric with excellent ferroelectric performance. The ferroelectric functional material is prepared by reacting a cupric salt solution with a methane dicarboxylic acid solution at first, then reacting with a phenanthroline solution and carrying out crystallization under the condition that the pH value is 3.0-5.0, has the advantages of less flow, simple process, low requirements for equipment, no pollution and low cost, and is easy to realize industrialization.
Owner:NINGBO UNIV

Preparation method of A-site ion-doped sodium bismuth titanate based lead-free piezoelectric ceramic and product obtained by method

InactiveCN109851354AOptimizing Sintering TemperatureEnhance resilienceSodium bismuth titanatePotassium carbonate
The invention discloses an A-site ion-doped sodium bismuth titanate based lead-free piezoelectric ceramic and a preparation method thereof. The sodium bismuth titanate based lead-free piezoelectric ceramic has the following chemical formula: 0.852{Bi<0.5>[Na<1-x>Li<x>]<0.5>}TiO<3>-0.110(Bi<0.5>K<0.5>)TiO<3>-0.038BaTiO<3>, and the chemical formula is denoted as BNKBT-xLi, wherein 0.12<=x<=0.13. Thepreparation method comprises the following steps: respectively preparing sodium carbonate, potassium carbonate, bismuth trioxide, titanium dioxide, lithium carbonate and barium carbonate according tothe chemical formula, performing ball milling, performing drying, performing pre-synthesis on the mixed raw materials at 800-900 DEG C, performing granulation, performing molding, performing debinding, and performing sintering at 1100-1140 DEG C to obtain the high-performance A-site ion-doped modified sodium bismuth titanate based lead-free piezoelectric ceramic. The method provided by the invention not only optimizes sintering temperature, reduces volatilization of an alkali metal, but also improves strain performance, wherein the maximum strain S is 0.42%, the inverse piezoelectric coefficient d33* is 760 pm/V, and the saturation polarization intensity Ps is 34-38 [mu]C/cm<2>.
Owner:TIANJIN UNIV

A forming device and method for a thin-walled sleeve-like magnetic material

The invention provides a forming device and a forming method for thin-wall sleeve magnetic materials, and relates to the field of powder metallurgy forming. The device comprises a powder forming machine and a pressing die; the fit clearance between a lower punch of the die and the inner wall of a punching hole is 5-8mum, and the fit clearance between an upper punch of the die and the punching hole is 5-8mum; the strength of a material adopted by effective working parts of a rod core, the upper punch and the lower punch, and a female die are respectively higher than the saturation polarization strength of soft magnetic material powder which needs to be pressed; tungsten steel of which the compressive strength is more than HRA89 degrees is adopted by the effective working parts of inner walls of the upper punch and the lower punch and the rod core; high-speed steel is adopted by the female die and a substrate of the pressing die, i.e. the upper punch and the lower punch are both of welding structures of the tungsten steel and the high-speed steel. According to the forming device and the forming method provided by the invention, the pressing effect of the soft magnetic powder is enhanced, so that the density of all parts of a formed thin-wall sleeve is uniform, and the thin-wall sleeve has higher dimensional accuracy.
Owner:PINGHU GEOR CHI ELECTRONICS CO LTD

Organic molecular ferroelectric crystal di-n-butylamine difluoromonochloroacetate and its preparation method and use

The invention relates to an organic molecular ferroelectric crystal di-n-butylamine difluoromonochloroacetate, a preparation method therefor and use of the organic molecular ferroelectric crystal di-n-butylamine difluoromonochloroacetate. Proven by tests on electric hysteresis loop of the organic molecular ferroelectric crystal material, i.e., di-n-butylamine difluoromonochloroacetate through a Sawyer-Tower circuit, the material shows good ferroelectric properties in a ferroelectric phase and has relatively high saturation polarization strength reaching 3.9[mu]c / cm<2> and moderate coercive field about 12.4kV / cm. Proven by variable temperature nonlinear tests, the material does not have obvious second-order nonlinear frequency-doubled signals in a paraelectric phase, obvious second-order nonlinear frequency-doubled signals appear when the temperature is cooled to Curie temperature (243K), the strength value of the nonlinear signals is saturated along with decrease of temperature, excellent nonlinear on / off performance is shown in an entire test temperature range, the on / off ratio reaches 28, and the repeatability is relatively good. The reaction is simple, and the conditions are moderate.
Owner:FUJIAN INST OF RES ON THE STRUCTURE OF MATTER CHINESE ACAD OF SCI
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