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30 results about "Zirconium(IV) sulfate" patented technology

Zirconium(IV) sulfate is the name for a family of inorganic compounds with the formula Zr(SO₄)₂(H₂O)ₙ where n = 0, 4, 5, 7. These species are related by the degree of hydration. They are white or colourless solids that are soluble in water.

Cerium oxide and zirconium oxide based composite rare earth oxide with favorable ageing resistance and high reduction activity and preparation method of cerium oxide and zirconium oxide based composite rare earth oxide

The invention discloses a preparation method of a cerium oxide and zirconium oxide based composite rare earth oxide. The method comprises the following steps of: (1) weighting zircon salt with a certain mass and preparing a zircon salt solution; (2) mixing urea and sulfuric acid or sulfate to prepare an activating agent solution; (3) heating the zircon salt solution under the room temperature, meanwhile, slowly and dropwise adding the activating agent solution, controlling the temperature rise speed to ensure that the temperature is raised to 60 DEG C after the addition of the activating agent solution is finished, continuing to raising the temperature to 90-95 DEG C, and keeping the temperature for 20-100min to form a basic zirconium sulfate composite salt precursor solution; (4) preparing soluble cerate and rare earth metal salt, adding the soluble cerate and the rare earth metal salt into the basic zirconium sulfate composite salt precursor solution, and settling by using a soluble hydroxide or an aqueous solution of ammonia; and (5) filtering and cleaning precipitates, and then, calcining the precipitates to obtain the cerium oxide and zirconium oxide based composite rare earth oxide. The cerium oxide and zirconium oxide based composite rare earth oxide prepared by using the method provided by the invention has favorable ageing resistance and high reduction activity.
Owner:CHAOZHOU THREE CIRCLE GRP

Preparation method of molecular sieve composite catalyst Fe2O3/ZrO2/SO42 for desorbing CO2-rich amine solution

The invention discloses a preparation method of a molecular sieve composite catalyst Fe2O3/ZrO2/SO42 for desorbing a CO2-rich amine solution. The composite catalyst is obtained by loading Fe2O3 modified ultrastrong solid acid catalyst ZrO2/SO42- onto a carrier molecular sieve. The preparation method comprises the following steps: dissolving soluble iron salt and zirconium sulfate into a methanol solution to obtain a mixed solution A; heating the mixed solution A for one hour at the condition of 50 DEG C to obtain a mixed solution B; cooling the mixed solution B to the room temperature, addingmolecular sieve powder, and stirring for 5 hours to obtain a mixed solution C; ultrasonically treating the mixed solution C for more than 0.5 hour to obtain a mixed solution D; and drying and calcining the mixed solution D to obtain the molecular sieve composite catalyst Fe2O3/ZrO2/SO42. Compared with the prior art, the catalyst of the invention is simple in preparation process, cheap and easy inobtaining raw materials; the catalytic desorption performance is better than that of the traditional molecular sieve catalyst, a single metal oxide and a single metal oxide physically mixed catalyst;the catalyst is easy to separate, good in stability and recyclable; and the absorption performance for carbon dioxide of the amine solution is not influenced.
Owner:HUNAN UNIV

A kind of methane halogen oxidation catalyst and its preparation method and application

The invention discloses a catalyst for methane oxyhalogenation as well as a preparation method and an application of the catalyst. The core of the catalyst is zinc supported alumina, wherein content of alumina L acid is smaller than 0.2 mmol.g<-1>; BET specific surface area is 200-350m<2> / g; pore volume is 0.3-0.6 ml / g; the shell is alumina containing zirconium sulfate solid acid and a molecular sieve, and the molecular sieve is at least one of a 5A molecular sieve, a 13X molecular sieve and a mordenite molecular sieve; the weight ratio of zinc supported alumina to alumina containing zirconiumsulfate solid acid and the molecular sieve is 10:1-2:1; based on the weight of alumina containing zirconium sulfate solid acid and the molecular sieve as the baseline, the weight content of zirconiumsulfate solid acid is 8wt%-15wt%, and the content of the molecular sieve is 3wt%-7wt%; based on the weight of zinc supported alumina as the baseline, content of zinc in terms of oxide is 5wt%-30wt%.The catalyst has the advantages that methane conversion rate and selectivity of halomethane as a target product are increased simultaneously, deep oxidation of halomethane is inhibited, and yield of halomethane is increased obviously.
Owner:FUSHUN RES INST OF PETROLEUM & PETROCHEMICALS SINOPEC CORP +1

Titanium-zirconium cross-linking agent and preparation method thereof

The invention belongs to the technical field of cross-linking agent preparation, and provides a titanium-zirconium cross-linking agent and a preparation method thereof. The titanium-zirconium cross-linking agent provided by the invention is prepared from the following raw materials: inorganic titanium, a ligand, inorganic zirconium, protonic acid and water, the inorganic titanium comprises titanium phosphate and/or titanium sulfate; the ligand comprises one or more of diethanol amine, triethanolamine, ammonium citrate and sodium gluconate; the inorganic zirconium comprises zirconium oxychloride and/or zirconium sulfate. According to the titanium-zirconium cross-linking agent, the titanium cross-linking agent and the zirconium cross-linking agent are introduced at the same time, so that the titanium-zirconium cross-linking agent has the advantages of the titanium cross-linking agent and the zirconium cross-linking agent at the same time, and the pH application range of the titanium-zirconium cross-linking agent is widened; meanwhile, the titanium-zirconium cross-linking agent has excellent temperature resistance. In addition, through selection of inorganic titanium, inorganic zirconium and the ligand, generation of alcohol small molecular compounds in the preparation process is avoided, and the titanium-zirconium cross-linking agent is good in stability and environmentally friendly.
Owner:昆山京昆油田化学科技有限公司

Magnetic porous iron-zirconium bimetal composite coagulant aid as well as preparation method and application thereof

The invention discloses a magnetic porous iron-zirconium bimetal composite coagulant aid as well as a preparation method and application thereof. Zirconium sulfate and ferric sulfate are dispersed inpure water, the pH is adjusted to be weakly alkaline, glacial acetic acid is added under the heating condition for a reaction to obtain an iron hydrate / zirconium oxide colloidal solution, and the ironhydrate / zirconium oxide colloidal solution reacts under the high-pressure and high-temperature atmosphere to obtain a target product. The synthesis process is simple, the surface of the prepared magnetic porous iron-zirconium bimetal composite coagulant aid is rich in hydroxyl, sulfate radical active groups and metal ion active sites, the coagulant aid exists in a water body in a colloid form, and the two effects of fluorine ion rapid adsorption and rapid coagulation assistance can be achieved at the same time. After a conventional flocculating agent is added, the colloid state can be immediately converted into a floc state and finally settles down, rapid separation of water and mud is achieved, secondary pollution to a water body is avoided, and the used magnetic porous iron-zirconium double-metal composite coagulant aid can be recycled and reused through soaking, magnetic recovery and drying.
Owner:HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI

Recycling method of liquid zirconium sulfate hydrolysate for coating rutile titanium dioxide

The embodiment of the invention discloses a recycling method of liquid zirconium sulfate hydrolysate for coating rutile type titanium dioxide, and particularly relates to the field of coating of rutile type titanium dioxide, which comprises the following steps: step 1, zirconium slag comes from hydrolysate in a storage tank of zirconium sulfate solution for coating rutile type titanium dioxide, adding a proper amount of conversion accelerant according to the amount of the zirconium slag, and then performing crushing treatment; 2, adding zirconium slag and sulfuric acid mother liquor into the beaker, and stirring and mixing; 3, slowly pouring sulfuric acid with the concentration of 98% into the boiler, stirring, and controlling the reaction temperature and the reaction time; according to the method, external heating is not needed when the zirconium sulfate solution is prepared from the zirconium slag, the recycling rate of the zirconium slag reaches 99% or above, the problem of recycling of zirconium sulfate hydrolysate for rutile titanium dioxide coating is solved, discarding of waste in the storage stage of zirconium sulfate is reduced, the technological process for converting the zirconium slag into zirconium sulfate is shortened, and the production cost is reduced. And the reaction rate of the zirconium slag in the sulfuric acid solution is improved.
Owner:重庆思必水处理材料有限公司

A kind of magnetic porous iron-zirconium bimetal composite coagulation aid and its preparation method and application

The invention discloses a magnetic porous iron-zirconium bimetal composite coagulation aid and its preparation method and application. Zirconium sulfate and iron sulfate are dispersed in pure water, the pH is adjusted to weak alkalinity, and glacial acetic acid is added under heating conditions for reaction. Finally, a hydrated iron / zirconium oxide colloidal solution is obtained, and the hydrated iron / zirconium oxide colloidal solution is reacted under a high-pressure and high-temperature atmosphere to obtain the target product. The synthesis process of the present invention is simple, and the surface of the prepared magnetic porous iron-zirconium bimetallic composite coagulant is rich in hydroxyl groups, sulfate radical active groups and metal ion active sites, and exists in the form of colloids in water bodies, which can simultaneously realize rapid It has two functions of adsorption and rapid coagulation aid. After adding a conventional flocculant, the colloidal state will immediately change into a floc state, and finally settle down to achieve rapid separation of water and mud without causing secondary pollution to the water body. After use, the magnetic porous iron-zirconium bimetallic composite coagulant aid is soaked Magnetic recovery, drying can be recycled.
Owner:HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI
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