The invention relates to a device for collecting vapor in flue gas. The device comprises a heat exchange unit and a vapor collecting unit, an air channel is arranged on the upper portion of the heat exchange unit, a flue gas channel is arranged on the lower portion of the heat exchange unit, the heat exchange unit is connected with the vapor collecting unit through the flue gas channel, the bottom of the flue gas channel is provided with a plurality of drain pipes, and the vapor collecting unit comprises a plurality of cold water sprayers and a vapor collector. Air exchanges heat with the flue gas through the heat exchange unit, part of the vapor in the flue gas is condensed, the flue gas flows to the vapor collecting unit and is further cooled, the vapor in the flue gas is further collected, and the low-temperature flue gas is discharged. Compared with the prior art, the device is simple, low in cost, capable of continuously running, good in flue gas recovery effect and high in universality, running cost can be greatly reduced, economical efficiency is improved, the emission problem of the vapor is effectively solved, and environmental protection level can be improved.