The invention belongs to the technical field of silicon dioxide, and in particular relates to a preparation method of silicon dioxide with high oil absorption value and high water absorption capacity for washing powder. The method comprises: S1, preparing S into a sodium silicate solution and a sodium hydrogen carbonate solution; S2, adding water into a reaction tank, performing heating, and simultaneously, dropwise adding the sodium silicate solution and the sodium hydrogen carbonate solution; S3, performing heating, continuously adding the sodium silicate solution, then dropwise adding the sodium hydrogen carbonate solution, performing titration of sulfuric acid until the end point, and performing aging to obtain a head product; S4, performing pressure filtration on the head product, then putting the head product into an agitator tank, adding a mixed solution of hydrogen peroxide and sulfuric acid, and performing agitation to obtain silicon dioxide; and S5, performing pressure filtration washing on the obtained silicon dioxide, and performing crushing to obtain a product. The silicon dioxide prepared by the method has high oil absorption value and high water absorption capacity, and can be used as a detergent assistant to enable the washing powder to have better solubility, dispersity, adsorbability and decontamination ability.