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49results about How to "Excellent hydrogen resistance" patented technology

Two-dimensional material adjusting and controlling silicon-carbon composite structure hydrogen resisting coating and preparing method thereof

The invention discloses a two-dimensional material adjusting and controlling silicon-carbon composite structure hydrogen resisting coating. The two-dimensional material adjusting and controlling silicon-carbon composite structure hydrogen resisting coating is characterized in that a coating structure comprises a silicon-carbon compound and a two-dimensional material; a two-dimensional material coating is formed by stacking graphene of a two-dimensional structure or hexagonal boron nitride of a two-dimensional structure or molybdenum disulfide of a molybdenum disulfide layer by layer, the layer number ranges from 1 to 10, and the thickness of the two-dimensional material coating ranges from 0.34 nm to 28 nm; and the silicon-carbon compound is formed by sputtering a silicon carbide target material, and the thickness of the silicon-carbon compound ranges from 0.5 micron to 2 microns. A preparing method of the two-dimensional material adjusting and controlling silicon-carbon composite structure hydrogen resisting coating includes the step that the two-dimensional material is prepared by adopting a chemical vapor deposition (CVD) technology and an ion beam sputtering deposition (IBSD) technology and with the combination of an etching transferring technology. A composite coating technology is adopted and has a hydrogen resisting effect superior to that of a single coating; introduction of the two-dimensional material is brought forwards for the first time on the basis of an original silicon-carbon compound hydrogen resisting coating; and by the adoption of an existing technological method, composite structures of different forms are designed and prepared, and the layer number is taken into consideration.
Owner:BEIHANG UNIV

Hydrogen-resistance permeation layer on surface of metal hydride and preparation method thereof

The invention relates to a preparation method for a hydrogen-resistance permeation layer on the surface of metal hydride. According to the preparation method for the hydrogen-resistance permeation layer on the surface of the metal hydride, source materials containing carbon oxygen or nitrogen oxygen or carbon-nitrogen oxygen are sealed in a reaction vessel with metal hydride matrices, the pressure is controlled between 1.010<5> Pa-101 kPa, and the temperature is controlled to rise from the room temperature to 200-900 DEG C; the carbon oxygen or the nitrogen oxygen or the carbon-nitrogen oxygen is diffused to the surfaces of the metal hydride matrices and conducted in-situ reactions with metal elements of the matrices; and the dense and continuous composite hydrogen-resistance permeation layer which contains the carbon oxygen or the nitrogen oxygen or the carbon-nitrogen oxygen can be obtained after cooling. The hydrogen-resistance permeation layer is tightly combined with the matrices, is moderate in thickness, has an excellent hydrogen-resistance performance and can effectively prevent the hydrogen desorption of the metal hydride when used at the temperature of 200-900 DEG C. The hydrogen-resistance permeation layer on the surface of the metal hydride and the preparation method thereof are simple in operation, high in adaptability, and are not restricted by shapes and structures of complex matrices.
Owner:有研资源环境技术研究院(北京)有限公司

Metal uranium surface water-blocking hydrogen-blocking Al/Al2O3 composite plating layer and preparing method thereof

The invention discloses a metal uranium surface water-blocking hydrogen-blocking Al/Al2O3 composite plating layer and a preparing method thereof. The purpose is to develop the corrosion-resistant plating layer which has high density and particularly can effectively block water and hydrogen penetration so as to solve the problem about surface corrosion of metal uranium materials. The composite plating layer uses uranium as a base body and is formed by alternately depositing an Al plating layer and an Al2O3 plating layer. According to the composite plating layer and the preparing method, the aluminum oxide plating layer has a function of closing pores of the aluminum plating layer, and the following effects are achieved, wherein on one hand, introduction of the aluminum oxide plating layer prevents continuous growth of columnar grains of the aluminum plating layer, so that penetrating holes and defects in the plating layer are greatly reduced, the compactness of the plating layer is improved, and the number of permeation channels of corrosive media such as water and hydrogen is significantly reduced; and on the other hand, aluminum oxide is of a dense structure, is stable in performance and low in hydrogen permeability and can more effectively block penetration of small atomic size corrosion media such as hydrogen, and the protection performance of the plating layer on the base body is improved. It is determined that the composite plating layer can effectively block penetration of environmental atmospheres such as the water and the hydrogen on the uranium.
Owner:MATERIAL INST OF CHINA ACADEMY OF ENG PHYSICS

A kind of high bonding strength aluminum oxide resistance to hydrogen permeation and corrosion resistance insulation layer and its preparation method and application

The invention relates to a high-binding-strength aluminum oxide resistance to hydrogen permeation and corrosion-resistant insulating layer and a preparation method and application thereof. The coating can be prepared by cold spraying, chemical vapor deposition, magnetron sputtering, thermal spraying and other methods on the surface of the substrate to prepare a layer of iron-chromium-aluminum alloy mixed in a certain proportion, and then obtain a thickness of 0.05-1μm by thermal oxidation. α‑Al is dense and has good bonding strength with the substrate, and has excellent hydrogen permeation resistance effect 2 o 3 Oxide layer, the temperature of the substrate during all operations can be controlled below 800°C. In addition to excellent hydrogen permeation resistance, strong self-healing ability and corrosion resistance and insulation ability, the hydrogen permeable layer provided by the present invention has the biggest outstanding advantage of excellent bonding strength with the substrate. The hydrogen-resistant coating can be used as a hydrogen-permeable barrier layer for stainless steel structural parts, especially for a hydrogen-permeable barrier layer on the surface of fusion reactor inner cladding components.
Owner:HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI

Composite proton conductive ceramic electrolyte film as well as preparation method and application thereof

The invention discloses a composite proton conductive ceramic electrolyte film as well as a preparation method and application thereof. The film is formed on the surface of a ceramic tube and is a composite film formed by alternately compounding multiple layers of film materials SrCe<1-x>Yb<x>O<3-alpha> and SrCe<1-x>Er<x>O<3-alpha>, the innermost layer is the SrCe<1-x>Yb<x>O<3-alpha> film, and theoutermost layer is the SrCe<1-x>Er<x>O<3-alpha> film. The preparation method comprises the following steps: (1) carrying out ultrasonic cleaning on the surface of the ceramic tube for 15-30 minutes,and drying; and (2) sequentially and alternately forming a SrCe<1-x>Yb<x>O<3-alpha> film and a SrCe<1-x>Er<x>O<3-alpha> film on the surface of the ceramic tube by adopting a metal organic chemical vapor deposition technology, and finally obtaining the multi-layer SrCe<1-x>Yb<x>O<3-alpha>/SrCe<1-x>Er<x>O<3-alpha> composite proton conductive ceramic electrolyte film. According to the preparation method, the preparation of the composite proton conductive ceramic electrolyte film alternately formed by SrCe<1-x>Yb<x>O<3-alpha> and SrCe<1-x>Er<x>O<3-alpha> is realized on the surface of the ceramic tube for the first time, and the film is good in combination with a matrix, high in compactness, uniform, stable and excellent in hydrogen resistance.
Owner:GRIMAT ENG INST CO LTD

A kind of disperse proton conductive ceramic electrolyte film and preparation method thereof

The invention discloses a dispersed proton conductive ceramic electrolyte membrane and a preparation method thereof. The film is formed on the surface of the ceramic tube and is made of film material SrCe 1‑x Yb x o 3‑α and SrCe 1‑ x Er x o 3‑α composed of dispersed thin films, in which SrCe 1‑x Yb x o 3‑α Main phase, SrCe 1‑x Er x o 3‑α Dispersed in the main phase. The preparation method comprises the following steps: (1) ultrasonically cleaning the surface of the ceramic tube for 15-30 min, and drying; (2) simultaneously depositing SrCe on the surface of the ceramic tube by metal-organic chemical vapor deposition technology. 1‑x Yb x o 3‑α and SrCe 1‑x Er x o 3‑α , the metal reaction sources are Yb organic reaction source and Er organic reaction source respectively, and the carrier gas is H 2 ; By adjusting the reaction source temperature and reaction time to make SrCe 1‑x Yb x o 3‑α phase becomes the main phase, and finally a dispersed proton-conducting ceramic electrolyte film is obtained. The film of the present invention has the characteristics of high bonding strength with the substrate, high compactness, uniformity and stability, and excellent hydrogen resistance performance, and can be applied to solid oxide fuel cells, electrolysis of water for efficient production of hydrogen, synthesis of ammonia under normal pressure, separation and purification of hydrogen, etc. aspect.
Owner:GRIMAT ENG INST CO LTD
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