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35results about How to "Grain refinement is obvious" patented technology

Lead-free electroless tin plating solution

InactiveCN102994994AEnables continuous autocatalytic depositionReduce typesLiquid/solution decomposition chemical coatingSolubilityPorosity
The invention relates to a lead-free electroless tin plating solution. The lead-free electroless tin plating solution is characterized by comprising the following components: 20 to 30g / L of stannous mono-sulphate, 60 to 120g / L of thiourea, 15 to 25g / L of citric acid, 20 to 50g / L of sulfur dioxide, 3 to 5g / L of ethylene diamine tetraacetic acid, 0.01 to 0.05g / L of polyethylene glycol, 20 to 55m / L of 98% of concentrated sulfuric acid, 0.5 to 1.0g / L of gelatin, and the balance of regulator. The lead-free electroless tin plating solution has the advantages that few categories of chemical materials are used and cost is low; the tin can be continuously deposited at a high speed on copper and a copper alloy substrate, thus semi-bright chemical coatings with different thicknesses can be produced, and the flatness of the chemical coatings can be improved; and the lead-free electroless tin plating solution is remarkable in grain refinement, low in porosity, simple in formula of plating solution, easy to control, stable in plating solution, long in service life and high in stability in batch production; and polyethylene glycol is a nontoxic and nonirritating substance with high water solubility, and can be combined with other materials without producing harmful substances.
Owner:NANTONG HUIFENG ELECTRONICS TECH

Method for preparing dispersion strengthened copper-based composites through equal channel angular pressing (ECAP)

Disclosed is a method for preparing dispersion strengthened copper-based composites through equal channel angular pressing (ECAP). The dispersion strengthened copper-based composites after hot extrusion, rolling, drawing or rotary swaging forming are sent to an ECAP die (3) which is preheated to 100-500 DEG C and coated with lubricants after preheating at the temperature of 200-900 DEG C and preserving heat for 0.5-5h; dispersion strengthened copper-based composite sticks, plates, tubes, square materials and the like are pressed and formed under pressing pressure (1) of 100-1000MPa at the pressing speed of 1-100 mm/min; the next pressing process is performed after each pressing process, and altogether 2-10 pressing processes are performed. According to the method, grains of the dispersion strengthened copper-based composites are refined effectively; comprehensive performance such as strength, hardness and electric conductivity of the dispersion strengthened copper-based composites is improved; the method has the advantages that operation is easy, machining efficiency is high, and cost is low. The dispersion strengthened copper-based composites prepared through the method can be widely applied to the aviation field, the aerospace field, the electronic field, the manufacturing field and the like.
Owner:INST OF APPLIED PHYSICS JIANGXI ACADEMY OF SCI

Preparation method of high-wear-resistance high-hardness titanium alloy composite sleeve

The invention discloses a preparation method of a high-wear-resistance high-hardness titanium alloy composite sleeve. The preparation method comprises the following steps that 1, shot blasting treatment is carried out on the outer surface of a conventional titanium alloy composite sleeve; 2, 2, pretreatment is carried out on the outer surface of the titanium alloy composite sleeve; 3, the titaniumalloy composite sleeve is fixed into a micro-arc oxidation groove set; 4, micro-arc oxidation treatment is carried out on the outer surface of the titanium alloy composite sleeve; 5, the outer surface of the titanium alloy composite sleeve obtained after micro-arc oxidation is cleaned and dried. An outer surface micro-arc oxidation coating of the titanium alloy composite sleeve adopting shot blasting is uniform and compact, the hardness of the surface layer of the sleeve is increased, and the titanium alloy composite sleeve has certain wear resistance and mechanical stability. According to the method, the conventional titanium alloy composite sleeve is subjected to shot blasting treatment and micro-arc oxidation treatment, and a protective layer high in hardness and resistant to wear andcorrosion is formed on the outer surface layer of the titanium alloy composite sleeve, so that the service life of the titanium alloy composite sleeve is prolonged, the production cost is reduced, andthe application of the technology in the field of oil and gas wells is further accelerated.
Owner:XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY

Iron-based wear-resistant composite material and preparation method thereof

The invention discloses an iron-based wear-resistant composite material and a preparation method thereof. The preparation method comprises the following steps: preparing an iron-based wear-resistant composite coating on the surface of an iron-based alloy matrix material by using iron-based composite powder by using a laser cladding method to obtain a composite body; polishing and cleaning the surface of the composite body; then carrying out laser shock, and surface enhancement treatment of the iron-based wear-resistant composite coating is achieved; performing cyclic heat treatment on the composite with the surface subjected to laser shock to eliminate residual stress; and the iron-based composite powder is obtained by uniformly mixing micron La2O3 powder, micron Al2O3 powder and micron FeCrNiSiB powder, carrying out liquid nitrogen circulation subzero treatment and drying, and the iron-based composite powder contains the following components in percentage by mass: 0.05%-10% of the micron La2O3 powder, 0.1%-45% of the micron Al2O3 powder and 50%-95% of the micron FeCrNiSiB powder. According to the iron-based wear-resistant composite material and the preparation method thereof provided by the invention, the composite coating with good performance is prepared on the surface of an iron-based alloy material, the service life of an iron-based alloy matrix is prolonged, and the preparation method has great significance in repairing and reconstruction of engineering machinery.
Owner:XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY

Tantalum-containing copper alloy wire/strip and preparation method thereof

The invention provides a tantalum-containing copper alloy wire/strip comprising the following components of, by mass, 0.01%-1.0% of tantalum, 0.01%-1.0% of silver, 0.01%-0.5% of iron, and the balancecopper. The invention further provides a preparation method of the tantalum-containing copper alloy wire/strip. A continuous casting machine conducts high-temperature treatment on copper-tantalum intermediate alloy, silver, copper-iron intermediate alloy and copper, drawing casting is conducted after cooling, then repeated drawing is conducted, after micro machining, continuous heat treatment is conducted through annealing equipment, the tantalum-containing copper alloy wire is obtained, and the tantalum-containing copper alloy strip of the needed specifications is obtained through rolling ofa double-roller rolling mill. With adding of the tantalum, magnetoconductivity of the copper alloy is improved effectively, the strength of the copper alloy is improved through adding of the silver, good electroconductibility of the copper alloy wire/strip is ensured, magnetoconductivity of the copper alloy can be further enhanced through the iron element in the copper alloy, and the copper alloymaterial has good magnetoconductivity, electroconductibility and strength through the element combination of tantalum, silver, iron and copper.
Owner:HENAN POLYTECHNIC UNIV +2

Method for preparing aluminum-scandium alloy with high scandium content

The invention discloses a method for preparing an aluminum-scandium alloy with high scandium content. The method comprises the steps that metal scandium and metal aluminum are weighed according to thescandium content in the aluminum-scandium alloy needing to be prepared; the obtained materials are added into a medium-frequency induction melting furnace, continuously vacuumizing is carried out, and then heating is carried out to 1200-1600 DEG C to melt the metal scandium and the metal aluminum; after complete melting is achieved, alloy liquid is obtained, and heat preservation is carried out for 20-40 min; and high-purity argon is introduced in, the alloy liquid subjected to heat preservation is poured into a water-cooled copper die, circulating water is cooled to 1-15 DEG C by adopting amold circulating water refrigerating system, the cooled circulating water is introduced into the water-cooled copper die to circularly cool the alloy liquid, and cooling and solidifying of the alloy liquid can be completed within 3-8 seconds to obtain an aluminum-scandium alloy cast ingot with scandium content of 5%-99%. According to the method, rapid cooling can be achieved within 3-8 s, the aluminum-scandium alloy with high scandium content which is high in purity, high in compactness, low in segregation, uniform in component and low in cost can be prepared, and the requirement of the current market for the aluminum-scandium alloy with high scandium content is met.
Owner:HUNAN RARE EARTH METAL MATERIAL RES INST

Copper alloy strip containing tantalum and preparation method thereof

The invention provides a tantalum-containing copper alloy wire / ribbon, which comprises the following components in mass percentage: tantalum: 0.01-1.0%, silver: 0.01-1.0%, iron: 0.01-0.5%, and the balance is copper. It also provides a preparation method of tantalum-containing copper alloy wire / strip. The continuous casting machine performs high-temperature treatment on copper-tantalum master alloy, silver, copper-iron master alloy and copper, draws and casts after cooling, and then draws for many times. After processing, it is continuously heat-treated on annealing equipment to obtain tantalum-containing copper alloy wires, which are rolled into tantalum-containing copper alloy strips of required specifications by twin-roll rolling mills. The addition of tantalum in the present invention effectively improves the magnetic permeability of the copper alloy, the addition of silver improves the strength of the copper alloy, and ensures the good electrical conductivity of the copper alloy wire / band, and the iron element in the copper alloy is conducive to further strengthening the copper alloy. Magnetic permeability, the elemental combination of tantalum, silver, iron, and copper makes the copper alloy material have good magnetic permeability, electrical conductivity and high strength.
Owner:HENAN POLYTECHNIC UNIV +2

Continuously self-catalyzed deposition chemical plating solution of tin and using method thereof

InactiveCN101724834BEnables continuous autocatalytic depositionFast depositionLiquid/solution decomposition chemical coatingAntioxidantBenzaldehyde
The invention discloses continuously self-catalyzed deposition chemical plating solution of tin and a using method thereof. Half-bright and silvery-white tin-copper alloy deposition layers are obtained on pure copper and a copper alloy substrate. In the chemical plating solution, stannous chloride serves as a main salt, thiourea serves as a main complexing agent, trisodium citrate serves as an auxiliary complexing agent, sodium hypophosphite serves as a reducing agent, disodium ethylene diamine tetraacetate serves as an antioxidant, a hydrochloric acid serves as a stabilizing agent, gelatin serves as a leveling agent and benzaldehyde serves as an auxiliary brightening agent. The using method comprises the following operating conditions that: the pH value of the plating solution is 0.8 to 2.0; the temperature is 80 to 90 DEG C; the loading capacity is 0.8 to 1.5 dm2 / L; and the mechanical stirring speed is 50 to 100 rpm. The continuously self-catalyzed deposition chemical plating solution of the tin and the using method thereof have the advantages of capability of obtaining half-bright and silvery-while tin-copper alloy clad layers with different thicknesses by controlling chemical plating time, high deposition rate, remarkable grain refinement, improvement on surface evenness of the clad layer and batch production stability, secure interface combination, strong change resistance of the clad layer after being passivated, and broad application prospect in the products of deep hole elements, blind hole elements, difficult-to-handle miniature electronic components and parts, printed circuit boards PCBs and the like.
Owner:KUNMING UNIV OF SCI & TECH

A kind of iron-based wear-resistant composite material and preparation method thereof

The invention discloses an iron-based wear-resistant composite material and a preparation method thereof. The preparation method includes the following process: using a laser cladding method to prepare an iron-based wear-resistant composite coating on the surface of an iron-based alloy base material with iron-based composite powder. layer to obtain the composite body; the surface of the composite body is polished and cleaned; then laser shock is carried out to realize the surface enhancement treatment of the iron-based wear-resistant composite coating; the composite body subjected to laser shock on the surface is subjected to cyclic heat treatment to eliminate residual stress; The iron-based composite powder is micron La 2 o 3 Powder, Micron Al 2 o 3 The powder and micron FeCrNiSiB powder are uniformly mixed, cryogenically treated with liquid nitrogen circulation, and dried. In terms of mass percentage, the iron-based composite powder contains: 0.05% to 10% of micron La 2 o 3 Powder, 0.1%~45% micron Al 2 o 3 powder and 50% to 95% micron FeCrNiSiB powder. The invention improves the service life of the iron-based alloy matrix by preparing a composite coating with good performance on the surface of the iron-based alloy material, and has great significance for the repair and reconstruction of engineering machinery.
Owner:XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY
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