The invention discloses a preparation method of a high-adsorbability ion exchange resin for sewage treatment. The preparation method comprises the following steps: sending macroporous chloromethylatedpolystyrene resin into a piperazine aqueous solution for swelling, adding 2-aminoethanol, carrying out heating, stirring, cooling and washing, adding modified guar gum, stirring the mixture uniformly, and carrying out filtering, washing and drying to obtain pretreated polystyrene resin; and dropwise adding thionyl chloride into the pretreated polystyrene resin in an ice water bath, adjusting thetemperature, keeping the temperature, carrying out cooling, washing and filtering, sending the mixture into nitrobenzene for swelling, and adding trimethylamine for reaction to obtain the high-adsorbability ion exchange resin with for sewage treatment. The modified guar gum is prepared by the following processes: mixing chitosan and glacial acetic acid uniformly, adding water, stirring the materials uniformly, adding polyethylene glycol, carrying out heating and stirring, then carrying out heating, adding guar gum and bamboo charcoal powder and stirring the materials to obtain the modified guar gum.