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978 results about "Poly methacrylate" patented technology

Highly purified tocopheryl phosphate, process for producing the same, analytical method therefor and cosmetic

Disclosed herein are a highly purified tocopheryl phosphate and / or a salt thereof (tocopheryl phosphates) wherein a P,P'-bistocopheryl hypophosphate and / or a salt thereof (P,P'-bistocopheryl diphoshates) is contained in a proportion of not higher than 3% by weight; a process for producing a highly purified tocopheryl phosphate and / or a salt thereof, which comprises the steps of reacting a tocopherol with an oxyphosphorus trihalide followed by treating with an acid or basic aqueous solution to thereby form tocopheryl phosphates (i) in which P,P'-bistocopheryl diphoshates (ii) formed as by-products are contained, hydrolyzing the P,P'-bistocopheryl diphoshates (ii) under acid condition, and, optionally, rendering the hydrolyzate neutral or basic under basic condition; and a method of analyzing tocopheryl phosphates, comprising analyzing a sample containing components (i) and (ii) with the use of a high-performance liquid chromatograph column packed with a gel of a polymethacrylate having, bonded thereto, long-chain alkyl groups. None or only an extremely minute amount of P,P'-bistocopheryl diphoshates are contained in the highly purified tocopheryl phosphates, so that the highly purified tocopheryl phosphates exhibit antioxidant and blood circulation promoting effects, have excellent water solubility, are powdery so that the handling thereof is extremely easy, are free from cutaneous irritation and allergenecity and ensure dermal safety. Therefore, the highly purified tocopheryl phosphates are useful as cosmetic ingredients. The amounts of components (i) and (ii) can be simply measured with high accuracy by the above method.
Owner:SHOWA DENKO KK

Plastic body provided with a microstructured surface

The invention relates to a process for the production of a plastics article with a microstructured surface via production of a composite composed of a backing layer composed of a thermoplastic or thermoelastic with one or more structure layers, characterized in that the structure layer(s) is/are composed of from 1 to 100% by weight of a polymethacrylate moulding composition which comprises from 80 to 100% by weight of free-radical-polymerized methyl methacrylate units and from 0 to 20% by weight of other comonomers capable of free-radical polymerization, and which has an average (weight-average) molar mass Mw of from 30 000 g/mol to 70 000 g/mol and, where appropriate, is present in a. mixture with up to 99% by weight of a polymethacrylate moulding composition which is composed of from 80 to 100% by weight of free-radical-polymerized methyl methacrylate units and from 0 to 20% by weight of other comonomers capable of free-radical polymerization, and which has an average (weight-average) molar mass Mw of from 90 000 g/mol to 200 000 g/mol and the structure layer(s) obtain microstructuring via known structuring processes, after production of the composite. The invention further relates to the plastics articles themselves which are capable of production according to the invention, and also to their uses.
Owner:ROEHM GMBH & CO KG

Polylactic acid resin composition, process for producing the same, biaxially stretched polylactic acid film, and molded articles thereof

The invention provides a resin composition containing poly(lactic acid) and a cellulosic ester, which are biomass type materials; a resin composition excellent in transparency, mechanical properties, and thermostability; a biaxially drawn film containing poly(lactic acid) and at least one compound selected from cellulosic esters, poly(meth)acrylates, and polyvinyl compounds having a glass transition temperature of 60° C. or higher; and a biaxially drawn film excellent in transparency, mechanical properties, and thermostability. The aims of the invention can be achieved by a resin composition obtained by melt-kneading a poly(lactic acid) polymer with a weight average molecular weight of 50,000 or higher and a cellulosic ester; a resin composition excellent in transparency and having luminous transmittance of 40% or higher for visible light with 400 nm; its production method; a molded article and a film made of the resin composition; a poly(lactic acid) biaxially drawn film containing a poly(lactic acid) polymer with a weight average molecular weight of 50,000 or higher and at least one compound selected from cellulosic esters, poly(meth)acrylates, and polyvinyl compounds having a glass transition temperature of 60° C. or higher; a poly(lactic acid) biaxially drawn film excellent in transparency and having film haze of 10% or lower; and a molded article made of the film.
Owner:TORAY IND INC

Process for preparation of high purity methacrylic acid

The present invention relates to a process for preparation of pure methacrylic acid, at least comprising the process steps: a) gas phase oxidation of a C4 compound to obtain a methacrylic acid-comprising gas phase, b) condensation of the methacrylic acid- comprising gas phase to obtain an aqueous methacrylic acid solution, c) separation of at least a part of the methacrylic acid from the aqueous methacrylic acid solution to obtain at least one crude methacrylic acid- comprising product; d) separation of at least a part of the methacrylic acid from the at least one crude methacrylic acid -comprising product by means of a thermal separa tion process to obtain a pure methacrylic acid. The invention also relates to method for preparing metacrylic acid ester by the high-purity methacrylic acid obtained by the process, metacrylic acid ester that can be obtained by the method, a method for preparing polymethacrylic acid analogue and polymethacrylic acid analogue obtained by the method, a method for preparing polymethacrylate and polymethacrylate obtained by the method, pure methacrylic acid that can be obtained by the inventive method and the use of the metacrylic acid ester obtained by the inventive method, as well as fibers, films, varnishes, coatings, molding materials, formed bodies, paper additives, leather additives, flocculants and drilling additives.
Owner:ROHM G M B H

Deepwater constant-rheology oil base drilling fluid

ActiveCN104861944ARaw material requirements are relaxedLow costDrilling compositionDimer acidWhite oil
The invention discloses a deepwater constant-rheology oil base drilling fluid applicable for deep sea drilling. The deepwater constant-rheology oil base drilling fluid applicable for deep sea drilling comprises the following components in parts by weight: 70-100 parts of white oil, 0-30 parts of a calcium chloride aqueous solution, 1.5-5 parts of a fluid type conditioning agent, 1-4 parts of an emulsifying agent, 0.5-2.5 parts of a wetting agent, 1-3.5 parts of organic soil used for drilling fluid, 1.5-5 parts of a filtrate reducer, 0.2-0.6 parts of calcium oxide and 0-260 parts of a weighting agent. The fluid type conditioning agent is at least one of ethylene-propylene copolymer, polymethacrylate, trimeric acid, phenolic resin, copolymer generated from reaction of dimer acid, cholamine and polyethylene polyamine and copolymer generated from reaction of acrylamide, styrene and methacrylic acid. The movable shearing force and six-speed viscometer of the oil base drilling fluid is respectively less than 6 r/min and 3 r/min, and the 10-min static shearing force can be kept steady within 4-65 DEG C; constant eheology is realized in the temperature range of the barrel of the deepwater drilling, technical demands on sea deepwater drilling can be satisfied, requirements on base oil raw material are loose, and the cost is low.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

Flame-retardant microcapsule as well as preparation method and application thereof

The invention discloses a flame-retardant microcapsule as well as a preparation method and application thereof. The flame-retardant microcapsule comprises a core material and a coating layer coating at the outer side of the core material, wherein the core material is liquid heptafluoropropane or liquid hexafluoropropane; and the coating layer is a polymethacrylate polymer and is prepared by polymerization by virtue of a suspension polymerization method. The flame-retardant microcapsule can be used as a flame-retardant filler singly, and also can be used as a flame-retardant filler together with magnesium hydroxide/aluminum hydroxide for preparing an electronic-pouring sealant in combination. The flame-retardant microcapsule disclosed by the invention is high in thermal stability and good in penetration resistance, and cannot generate leakage of the core material in a normal state; and only when subjected to high-temperature combustion, the coating layer is softened and the liquid core material is vaporized at the same time so that the internal pressure is increased and results in expansion breakage of the coating layer, and then the core material is released at last to quickly retard inflaming and put out a fire, so that the flame-retardant microcapsule has a broad use prospect in the field of preparation of the electronic-pouring sealant.
Owner:浙江中天东方氟硅材料股份有限公司
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