16results about How to "Avoid phase separation" patented technology

The invention relates to a bi-crosslinking cyanate ester-epoxy blended adhesive and a preparation method thereof, and relates to the technical field of high polymer materials, the adhesive comprises the following components in parts by weight: 45-85 parts of cyanate ester resin, 5-35 parts of epoxy resin, 0-20 parts of a reactive diluent, 2-6 parts of a bi-crosslinking curing agent and 0-50 parts of a functional filler, the bi-crosslinking curing agent has the following structure: R is alkyl, aliphatic amine or aryl; r'is a primary amino group and / or a secondary amino group, R ''is-C = N and / or-OCN, m is an integer from 1 to 3, and n is an integer from 1 to 2. By adding the double-crosslinking curing agent containing the amino group and the cyano group, the technical problems of high curing temperature, large stress after curing, poor temperature resistance of epoxy resin and the like of the existing cyanate ester resin system are solved, and the curing temperature, the bonding strength and the temperature resistance of the adhesive are balanced. The adhesive can be cured at the temperature lower than 90 DEG C, and has high glass transition temperature, low thermal weight loss and excellent adhesive property.

The application relates to the technical field of high polymer composite materials, and particularly discloses a resin applied to motor rotor carbon fiber winding and a preparation method thereof. The resin comprises the following raw materials: 40-60 parts of a tetrafunctional phenolic epoxy resin, 20-40 parts of a biphenyl type epoxy resin, 15-20 parts of a core-shell rubber, 0.1-0.2 parts of triphenylphosphine, 20-25 parts of a curing agent, 0.5-1 part of an accelerator, 3-5 parts of nano fillers, 1-2 parts of a silane coupling agent and 5-8 parts of an active diluent. The resin prepared by the application has excellent high-temperature resistance and high elongation at break, and can be applied to motor rotor carbon fiber winding.

The invention relates to the technical field of furan resin, in particular to high-strength furan resin as well as a preparation method and application thereof. The high-strength furan resin comprises the following components in parts by weight: 35-60 parts of furfuryl alcohol, 15-25 parts of formaldehyde, 5-10 parts of urea, 1-3 parts of a formaldehyde reducing agent and 3-5 parts of a cross-linking agent. The high-strength furan resin provided by the invention is high-performance furan resin with high mechanical strength, excellent moisture resistance and low free formaldehyde release, and has a wide application prospect in the field of casting. The introduced cross-linking agent can improve the cross-linking density, improve the tensile strength and avoid brittle failure. In addition, carboxyl in molecules of the cross-linking agent can adjust polarity and compatibility of the system, phase separation in storage and use processes is inhibited, and the storage stability of the resin is remarkably improved. The formaldehyde reducing agent introduced by the invention can be subjected to nucleophilic addition reaction with free formaldehyde in a system, so that the formaldehyde content can be efficiently and enduringly reduced, and the production and use environment can be improved.

The present application relates to the field of light stimulus response material, in particular to a kind of D-A structure regulation intramolecular charge transfer realizes double-wavelength stimulus response film long afterglow material and its preparation method and application, the film long afterglow material is host-guest doped type, the host is polyvinyl alcohol, the guest is D-A type triphenylphosphonium derivative.In the D-A structure regulation intramolecular charge transfer of the present application realizes double-wavelength stimulus response film long afterglow material, the single host has no photoexcitation phosphorescence characteristics, the single guest only has weak photoexcitation phosphorescence characteristics, and the film material presents the regulation of double-wavelength photoexcitation after being excited by ultraviolet light by being doped into film by guest and host.Based on D-A structure, the design idea and application prospect of single-component double-wavelength stimulus response film long afterglow material are greatly expanded.

The invention relates to the field of preparation of high polymer materials, in particular to a flexible irradiation crosslinking polyethylene foam material with high tensile strength and a preparation method thereof. According to the method, an elastic grafted polyion brush functional component is compounded with low-density polyethylene, so that the flexibility and tensile strength of the polyethylene foam can be effectively improved, and the polyethylene foam material with flexibility, high tensile strength and no corona gluing is obtained. The method disclosed by the invention has the following advantages: (1) the product is good in flexibility and high in tensile strength, and when the apparent density is lower than 0.1 g / cm < 3 > and the thickness is 1mm, the elastic modulus is below 0.8 MPa, the tensile strength is more than 1.6 MPa, and the elongation is more than 250%; (2) the cohesiveness of the product is high, the surface tension can reach 39 mN / m or above, the requirement of a gluing process is met, and the surface tension can be maintained for 6 months or above; and (3) the obtained product has wide application in the fields of precision mechanical shock absorption, electronic equipment, electronic screen protection and the like.

The invention relates to the technical field of coatings, in particular to water-based two-component low-temperature stoving varnish for a photovoltaic frame and a preparation method of the water-based two-component low-temperature stoving varnish. The water-based two-component low-temperature stoving varnish for the photovoltaic frame comprises a component A and a component B, comprising the following raw materials in parts by weight: 50-60 parts of resin, 10-25 parts of functional filler, 4-10 parts of a solvent, 0.2-0.5 part of a defoaming agent, 0.1-0.3 part of a wetting agent, 0.5-1.5 parts of a dispersing agent, 0.2-0.5 part of a thickening agent and 10-15 parts of water, and the component B is isocyanate. The low-temperature baking varnish prepared by the invention has good adhesive force and excellent corrosion resistance, aging resistance and wear resistance.

This application relates to the field of solar cells, disclosing perovskite materials, perovskite layers, their preparation methods, perovskite solar cells, and photovoltaic modules. The perovskite material has a band gap of 1.65 eV to 1.75 eV, and its chemical formula is ABX3, where A is an A-site cation, B is a B-site cation, and X is an X-site anion. The elements corresponding to the X-site anion include iodine, bromine, and chlorine. In the perovskite material, the mass percentage of bromine is 0.0001% to 0.0012%, and the mass percentage of chlorine is 0.0005% to 0.0020%. The perovskite material provided in this application, while meeting the wide band gap requirement, helps to avoid the formation of bromine-rich phases, thereby effectively preventing the separation of bromine and iodine phases and ensuring that the perovskite layer prepared using this material has high structural stability.

The present application belongs to the technical field of building coatings, and relates to a dual formaldehyde-removing and antibacterial coating and a preparation method thereof. The formaldehyde-removing and antibacterial coating prepared by the method can effectively remove formaldehyde under the action of ultraviolet light catalyst, and at the same time, the amino group can react with the negative charge on the bacterial cell membrane to cause the integrity of the bacterial cell membrane to be destroyed, so that the permeability of the bacterial cell membrane is changed, the cell contents are leaked, and finally the cell death is caused. The polyethylene imine grafted sodium alginate is introduced into the surface of titanium dioxide, so that the high adsorption performance of the alginate on formaldehyde and the dual formaldehyde-removing and antibacterial effect are utilized, and the dispersibility of the filler in the coating matrix is improved through the chemical bond and action between the amino group carried by the polyethylene imine and the epoxy resin. Therefore, the agglomeration problem of the inorganic filler is reduced, the formaldehyde-removing and antibacterial performance of the coating is improved, and the efficient and long-lasting application of the functional coating in the natural indoor environment is realized.

This invention relates to the field of advanced petrochemical new materials technology, and discloses a luminescent composite material, its preparation method, and its application. The composite material comprises the following components: homopolymer polypropylene, polybutylene succinate, a compatibility modification system, double-modified rare-earth strontium aluminate luminescent powder, dispersant, antioxidant, weathering agent, toughening agent, nucleating agent, and silane coupling agent. This invention employs a compatibility modification system composed of maleic anhydride-grafted PP-g-PBS copolymer and double-modified nano-montmorillonite. The maleic anhydride-grafted PP-g-PBS copolymer constructs a chemical link between the polypropylene and polybutylene succinate molecular chains through a grafting reaction, reducing the interfacial tension between the two resins. The double-modified nano-montmorillonite, after ionic liquid intercalation and silane grafting treatment, exhibits increased interlayer spacing and improved surface activity, uniformly dispersed in the matrix, and acts as a physical crosslinking point, improving the compatibility of the matrix resin and preventing phase separation.

The invention discloses plastic capable of transmitting infrared light and a preparation method thereof, and belongs to the field of high polymer material engineering. The plastic capable of transmitting infrared light, prepared by the invention, comprises the following raw material components in parts by mass: 100 parts of carrier resin, 20-30 parts of modified infrared transparent filler and 1-2 parts of auxiliaries, wherein the carrier resin is obtained by crosslinking an ethylene-vinyl acetate copolymer, polyethylene and vinyl cyclosiloxane; the vinyl cyclosiloxane comprises 1, 3, 5-trivinyl-1, 3, 5-trimethyl cyclotrisiloxane and tetramethyl tetravinyl cyclotetrasiloxane, and the vinyl cyclosiloxane comprises 1, 3, 5-trivinyl-1, 3, 5-trimethyl cyclotrisiloxane and tetramethyl tetravinyl The modified infrared transparent filler is obtained by modifying the infrared transparent filler with 1, 1, 3, 3-tetramethoxy-1, 3-dimethyl disiloxane; the infrared transparent filler is obtained by compounding barium fluoride and magnesium fluoride; the plastic capable of transmitting infrared light, prepared by the invention, is relatively good in mechanical property and high in infrared transmittance.

This invention relates to the field of silicone technology, specifically to a silicone composite thermally conductive material and its preparation process. The preparation process of a silicone composite thermally conductive material includes: pretreatment of graphene filler, preparation of modified graphene filler, preparation and modification of heterogeneous filler, and preparation of the silicone composite thermally conductive material. This invention utilizes modified graphene and the construction of a boron nitride-silica heterogeneous filler to form a multi-level thermally conductive network. Combined with electric field-induced ordered arrangement of fillers and pretreatment of graphene with chemically reduced gel and directional ice template, multiple methods are used synergistically to reduce interfacial thermal resistance and phonon scattering, constructing continuous thermally conductive channels. Simultaneously, it improves the structural uniformity, thermal conductivity stability, and mechanical properties of the composite material, effectively solving problems such as filler agglomeration and migration, and significantly improving the thermal conductivity of the silicone composite material.

The application provides a preparation method of wear-resistant and water-absorbing regenerated polyester fiber, comprising the following steps: S1. mesoporous silicon dioxide is immersed in a salt solution to obtain salt-containing silicon dioxide; S2. the salt-containing silicon dioxide and regenerated polyester chips are placed in a double-screw extruder for blending, extrusion and granulation to obtain modified regenerated polyester skin layer master batch; S3. sodium alginate / cellulose nanocrystal composite nanomaterial and regenerated polyester chips are placed in a double-screw extruder for blending, extrusion and granulation to obtain modified regenerated polyester core layer master batch; S4. the master batches prepared in S2 and S3 are respectively used as skin layer and core layer master batches, dry spinning is adopted, and drafting is performed to obtain a skin-core structure fiber; and S5. the skin-core structure fiber obtained in S4 is immersed in a saturated calcium chloride solution, vacuum impregnation is performed, and a wear-resistant and water-absorbing regenerated polyester fiber is obtained. The application prepares a regenerated polyester fiber which can realize the synergistic improvement of wear resistance and water absorption performance, and has mechanical stability and environmental protection.

The application relates to the technical field of building materials, in particular to a core material for A-grade fireproof metal composite board and a preparation method thereof. According to weight parts, the core material for the A-grade fireproof metal composite board comprises the following raw materials: 30-60 parts of base resin, 20-40 parts of flame retardant, 5-10 parts of modified montmorillonite, 0.5-2 parts of coupling agent, 0.5-3 parts of dispersant, 1-3 parts of compatibility agent and 0.5-3 parts of lubricant. The core material has excellent flame retardancy, antibacterial property and mechanical property.

The application relates to the technical field of organic silicon materials and ultraviolet light curing, and discloses a preparation method of a (methyl) acryloxy silane oligomer and a UV cured product thereof. The method comprises the following steps: carrying out hydrolysis condensation reaction on KH-572 monomers, an alcohol solvent and a catalyst at 40-60 DEG C, and preparing KH-572 oligomers with a polymerization degree of 5-25 by controlling the hydrolysis conditions; and mixing the oligomers with methyl methacrylate and a photoinitiator according to a weight ratio of (60-70):(40-30):(1-3), and then carrying out ultraviolet light curing forming. The application solves the technical problem that the KH-572 monomers cannot be directly used for curing by controllable polymerization, and the obtained cured coating has the advantages of compact structure and controllable hydrophobicity. The preparation method is simple in process and easy for industrialized production.

The application belongs to the technical field of resin materials for copper-clad plates, and particularly relates to a carbon-hydrogen resin composition for prepreg and a preparation method thereof. The carbon-hydrogen resin composition is prepared from the following raw materials in parts by mass: hyperbranched modified prepolymer resin 90-100 parts, inorganic filler 15-25 parts, silane coupling agent 0.2-0.4 parts, crosslinking agent 10-20 parts, initiator 0.8-1.5 parts, dibutyltin dilaurate 0.1-0.3 parts, antioxidant 0.5-1 part, and toluene 50-80 parts. The carbon-hydrogen resin composition prepared by the application has low dielectricity, high thermal conductivity, high heat resistance, high toughness, and excellent processing forming property.

The invention relates to the technical field of high polymer materials, in particular to a butyl acrylate-based high polymer dispersant for polyimide foam as well as a preparation method and application of the butyl acrylate-based high polymer dispersant. The dispersing agent is prepared from butyl acrylate (BA), methyl methacrylate (MIMA), polyethylene glycol monomethyl ether acrylate (PEG400MEA), hydroxyethyl methylacrylate (HEMA) and functional monomers through free radical polymerization reaction, wherein the mass percent of each monomer is as follows: 20%-40% of BA, 10%-25% of MMA, 35%-60% of PEG400MEA, 3%-10% of HEMA and 1%-5% of functional monomers. The functional monomer is one or more of acrylic acid, methacrylic acid, sodium p-styrene sulphonate or N-hydroxymethyl acrylamide. In the preparation process, peroxide or an azo substance initiator is adopted, and free radical reaction is carried out under the protection of inert gas. The dispersant belongs to anionic macromolecules, the weight-average molecular weight is 5000-50000, and the molecular weight dispersion coefficient (PDI 1.2-2.5).