The invention relates to a method for removing bromates from water by homogeneous photocatalysis. The method concretely comprises the following steps: adding a reducing agent to bromate-containing water to be treated, stirring the reducing agent and the water, irradiating the obtained solution with ultraviolet lights to generate reducing free radicals, and carrying out a reducing reaction to remove the bromates from the water. The reducing agent is irradiated with the ultraviolet lights to generate the reducing free radicals, a redox reaction occurs to achieve the purpose of removing bromates,the reducing agent is a conventional reducing agent having a low price, the bromate removal rate can reach 99% or more, and the final product is bromide ions. The method has the advantages of no introductio of other poisonous and harmful substances, simplicity in operation, mild and easily controlled conditions, achieving of the purpose of economical, efficient, secondary pollution-free, condition-mild and water adaptability-strong removal of the bromates from the water, great practical significance and wide prospect.