The invention relates to the technical field of materials, in particular to a
polyimide precursor and a preparation method thereof, a
polyimide precursor glue solution and a preparation method thereof, and a
polyimide film. The main chain of the polyimide precursor contains a keto-carbonyl self-sensitizing group and a group containing abstractable reactive
hydrogen, and the keto-carbonyl self-sensitizing group and the group can realize photo-crosslinking. Meanwhile, the polyimide precursor also has an ester-type photosensitive branched chain, and a cross-linked structure is easily formed under the action of a photo-crosslinking agent and the like, so that dual
sensitization is realized. The polyimide film prepared from the polyimide precursor not only retains the
high resolution of ester type photosensitive polyimide, but also reduces the proportion of photosensitive branched chains in the structure, so that the film shrinkage effect after curing is reduced, and the prepared polyimide film has both
high resolution and lower film thickness
shrinkage rate.