The invention relates to a high temperature explosion-proof device of a supercapacitor. The device comprises a main body, a capacitor body and connecting pieces, wherein a fixing plate is mounted in the main body, and a cavity is fixed to an inner side of the main body, the capacitor body is disposed inside the cavity, and pins are disposed at the top end of the capacitor body. The high-temperature explosion-proof device of the supercapacitor has the following beneficial effects: according to the invention, the main body, the cavity, the capacitor body, the fixing plate, a baffle plate, a reserved port and a spring shaft are disposed, the baffle constitutes an elastic rotating structure through the spring shaft and the fixing plate, and by the action of the cavity, the capacitor body can be placed. When the capacitor body is in the working state, a high temperature is generated, so that the airflow around the capacitor body expands, the outward thrust of the baffle can be given, and the rotation of the spring shaft can drive he baffle to rotate to create a gap with the fixing plate, so that the hot air flow can be quickly exchanged with the cold air flow inside the main body, thereby effectively preventing the high temperature explosion phenomenon of the capacitor body.