The invention discloses a metal surface silane treatment agent, which includes 20 to 30 parts by weight of silane coupling agent, 20 to 30 parts of film-forming agent, 5 to 7 parts of complexing agent, and 15 to 30 parts of pure water. The film-forming agent is a thickening agent, and the complexing agent is sodium citrate, which makes the present invention have high aging effect, super concentration, low carbon and energy saving, no residue, no phosphorus, no zinc, no chromium, no fluorine, Zirconium-free and superior environmental performance, the silane film has anti-corrosion properties and excellent adhesion properties.