The invention discloses a method of recycling residual alkali from
sodium tungstate solution in
tungsten smelting, which comprises the steps of: performing liquid-
solid separation on mixed material solution discharged from a
pressure cooking kettle through a press filter, pumping the filtrate into a three-effect
evaporation crystallizer through a pump, firstly preheating the filtrate in a first preheating
pipe, then conveying the filtrate into a first-effect
evaporation crystallizer, using the secondary vapor generated by first-effect
evaporation concentration as a heat source of second-effect evaporation concentration, and conveying
sodium tungstate crystals separated out from a second-effect evaporation crystallizer into a plate-and-frame
filter press to perform
solid-liquid separation; conveying the concentrated solution into a third-effect
concentrator, and performing
solid-liquid separation on the
sodium tungstate crystals separated out from a
crystallization kettle of the third-effect evaporation crystallizer; performing solid-liquid separation on the crystals separated out by the second-effect evaporation crystallizer and the third-effect evaporation crystallizer in the plate-and-frame
filter press; and conveying the filtrate into a
storage tank to return to the
pressure cooking procedure to prepare alkali, and discharging the filter residues in a dissolving tank. The method disclosed by the invention is mature in technique and equipment, high in
automation degree, high in
utilization rate of effective resources, good in energy-saving effect and high in recycled economic benefit, and the method is an important comprehensive recycling component in
tungsten smelting.