The invention provides
phosphorus-doped
porous graphene, a preparation method thereof and a method for catalyzing oxidation of
benzylamine. The
phosphorus-doped porous
grapheme is prepared from the steps that templating agent and a dispersion containing organic carbon and a
phosphorus source are mixed,
solvent in the
mixed solution is removed to obtain a mixture, the obtained mixture is calcined for 2-5 hours at the temperature of 200-700DEG C under an
inert atmosphere protection, then the templating agent is removed by means of
acid washing to obtain the phosphorus-doped
porous graphene. The method for catalyzing oxidation of
benzylamine comprises the following steps that the phosphorus-doped
porous graphene or the mixture of the templating agent and the phosphorus-doped porous
graphene are used as a catalyst and are reacted with
benzylamine under the action of
oxidizing agent to obtain N-benzylidenebutyramide. According to the phosphorus-doped porous
graphene, the preparation method thereof and the method for catalyzing oxidation of benzylamine, the templating agent is used for controlling the morphology, meanwhile, the organic compounds containing carbon and phosphorus are used as a
carbon source and a phosphorus source, and the phosphorus-doped porous
graphene is synthesized directly by means of
calcination, therefore, the preparation method has the advantages of being quick, convenient and fast, and being capable of being synthesized in one step, prone to large-scale production and so on.