The invention belongs to the technical field of ceramic and particularly relates to ceramic glaze with a water activating function, a preparation method thereof, ceramic prepared by the ceramic glaze and a preparation method of the ceramic. The ceramic glaze is prepared by, by mass percentage, 60-80% of ceramic glaze base material, 5-20% of ceramic additives with the water activating function, 5-8% of nano-zirconia, 0.5-5% of phosphate, 1-5% of nano cesium oxide, 2-8% of yttrium oxide, 1-5% of nano titanium dioxide and 3-8% of tourmaline. The preparation method of the ceramic glaze includes: ball milling the ceramic glaze base material until all the ceramic glaze base material can pass a 250-mesh sieve, adding the rest of components, adding water and ceramic diluent to prepare slurry, ball milling, and discharging. The ceramic glaze has the advantages that the ceramic glaze can acts on water molecular cluster structures to allow the hydrogen bonds to be destroyed and chemical bonds to break, large molecular clusters become small molecular clusters only containing 5-6 water molecules, toxic gas dissolved in water is released at the same time, the water become slightly alkaline, and the activity of the water is increased.