The invention belongs to the field of
lithium ion cell and specifically relates to a LiNi0.6-xCo0.2Mn0.2AlxO2-yFy positive
electrode material for the
lithium ion cell and a preparation method thereof. X is more than 0 and y is less than or equal to 0.05. The positive
electrode material is used for overcoming the defect of poor electrochemical performance of the Ni-Co
lithium manganate ternary positive
electrode material. According to the invention, a minute quantity of aluminum and
fluorine are doped, so that the positive
electrode material for the lithium
ion cell has higher
specific discharge capacity and excellent cycle performance; under a
room temperature environment, when the
voltage scope is 2.7-4.3V and the
constant current charge-
discharge multiplying power is 0.5C, the
specific discharge capacity of the material at the first time can reach 187.9mAh g<-1>, and after circulation for 20 times, the
specific discharge capacity still can reach 192.1mAh g1 and the capacity
retention ratio reaches up to 102.2%; when the
voltage scope is increased to 2.7-4.5V and the
constant current charge-
discharge multiplying power is 0.5C, the initial specific
discharge capacity of the material can reach 225.8mAh g<-1>, and after circulation for 20 times, the specific discharge capacity still can reach 190.2mAh g<-1> and the capacity
retention ratio reaches up to 84.2%. The preparation technique of the material is simple and controllable, the product purity is high, the chemical uniformity is high, the
crystal quality is high, the product grain is small and the size distribution is uniform.