The invention relates to a process for extracting
vanadium through alkaline leaching conducted after stone
coal oxidizing
roasting, and belongs to the technical field of
metallurgy and
chemical industry. The process is characterized by including the steps of firstly,
grinding stone
coal ore till the 200-mesh particles accounts for about 80% of the total amount, adding water to form balls, and conducting high-temperature
roasting in a flat
kiln; secondly, using NaOH and
sodium carbonate to conduct leaching together in the
vanadium leaching process, and conducting leaching for three hours at the temperature lower than 95 DEG C, wherein the massic volume ratio of stone
coal roasted product to leaching liquid is 1g / ml to 3g / ml, the additive amount of the NaOH is 40g / L, and the additive amount of the
sodium carbonate is 13.5g / L; thirdly, enabling the stone coal to enter a purifying
pool after primary leaching and washing are conducted so that the
solid-liquid separation can be achieved, stacking and storing the stone coal balls, enabling lixivium to directly flow back to be used for leaching
vanadium of newly added stone coal, adding leaching agents to the secondary lixivium according to the proportion of the NaOH to the leaching liquid, namely, 13.5g / L and the proportion of the
sodium carbonate to the leaching liquid, namely, 4.5g / L, and enabling the product to flow back to be used for leaching vanadium of stone coal balls which are added for the third time. The process has the advantages of being small in
pollution, high in vanadium extraction rate, few in heavy
metal impurities produced in the leaching process, small in
water consumption and the like, and has certain
economic benefits under the present technical condition.