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52 results about "Polyol formation" patented technology

Polyurethane adhesive for windshield applications

A polyurethane adhesive which is useful in bonding porous and non-porous surfaces is provided. The adhesive is especially useful in bonding windshield glass into automotive frames under a variety of environmental conditions, particularly in after market windshield replacement applications. The polyurethane includes at least one urethane prepolymer which is based on at least one thermoplastic polyol. In one embodiment, the urethane prepolymer may be formed from one or more polyisocyanates, one or more polyetherpolyols and one or more thermoplastic polyesterpolyols, wherein the prepolymer has a free isocyanate content of from about 0.6 to about 3.5% by weight, based on the weight of the polyurethane. In another embodiment, a one-part adhesive composition is provided which includes an isocyanate-functional and thermoplastic polyurethane prepolymer having a free isocyanate content of from about 0.6 to about 3.5% by weight, based on the weight of the polyurethane, and a combination of several catalysts which are capable of catalyzing the reaction of isocyanate moieties with isocyanate-reactive moieties while providing less temperature dependent catalyzing of the reaction between isocyanate moieties and water. Also provided is a process for bonding two or more substrates together utilizing the polyurethane adhesive. In automotive windshield replacement applications, the polyurethane adhesive allows for a sufficient working time and development of green strength to provide a safe drive-away time within 1 hour at a temperature from about 0 to about 100° C.
Owner:SIKA TECH AG

Polycarbonate resin composition, molded article and structure member for solar photovoltaic power generation

Provided are: a polycarbonate-based resin composition, including: (A) 100 parts by mass of a resin mixture formed of: 30 to 100 mass % of a PC-POS copolymer (A-1) which has constituent units represented by a general formula (I) and a general formula (II), and in which an average repetition number n of organosiloxane constituent units in the general formula (II) is 70 to 500; and 70 to 0 mass % of an aromatic polycarbonate resin (A-2) except the PC-POS copolymer (A-1); (B) 0.01 to 0.15 part by mass of an alkaline (earth) metal salt of an organic sulfonic acid; (C) 0.1 to 1 part by mass of a polytetrafluoroethylene having a fibril-forming ability; and (D) 2 to 15 parts by mass of titanium dioxide particles each having, on an outermost surface thereof, a coating layer formed of a polyol free of a nitrogen atom; a molded article obtained by molding the resin composition; and a structure member for solar photovoltaic power generation formed of the molded article. The polycarbonate-based resin composition, molded article, and structure member for solar photovoltaic power generation each have excellent flame retardancy and excellent tracking resistance without impairing a low-temperature impact characteristic which a PC-POS copolymer has.
Owner:IDEMITSU KOSAN CO LTD

Polycarbonate resin composition, molded article and structure member for solar photovoltaic power generation

Provided are: a polycarbonate-based resin composition, including: (A) 100 parts by mass of a resin mixture formed of: 30 to 100 mass % of a PC-POS copolymer (A-1) which has constituent units represented by a general formula (I) and a general formula (II), and in which an average repetition number n of organosiloxane constituent units in the general formula (II) is 70 to 500; and 70 to 0 mass % of an aromatic polycarbonate resin (A-2) except the PC-POS copolymer (A-1); (B) 0.01 to 0.15 part by mass of an alkaline (earth) metal salt of an organic sulfonic acid; (C) 0.1 to 1 part by mass of a polytetrafluoroethylene having a fibril-forming ability; and (D) 2 to 15 parts by mass of titanium dioxide particles each having, on an outermost surface thereof, a coating layer formed of a polyol free of a nitrogen atom; a molded article obtained by molding the resin composition; and a structure member for solar photovoltaic power generation formed of the molded article. The polycarbonate-based resin composition, molded article, and structure member for solar photovoltaic power generation each have excellent flame retardancy and excellent tracking resistance without impairing a low-temperature impact characteristic which a PC-POS copolymer has.
Owner:IDEMITSU KOSAN CO LTD

Preparation method and application of vanadyl phosphate catalyst

The invention relates to a vanadyl phosphate catalyst, an intensified preparation method by low congruent melting solvent, and application of the vanadyl phosphate catalyst. The method comprises the following steps: 1) mixing a vanadium source, low congruent melting solvent, benzyl alcohol and C3-C8 monohydric alcohol to obtain mixed materials, and reacting, wherein the low congruent melting solvent is formed by choline chloride and organic polyhydric alcohols; 2) mixing a reaction product obtained in 1) with a phosphorus source, raising the temperature to 100-200DEG C, and continuously reacting to obtain a vanadyl phosphate precursor; 3) roasting to obtain the vanadyl phosphate catalyst. The method is characterized in that green and low-price low congruent melting solvent is subjected tointensified preparation to obtain the vanadyl phosphate catalyst, the defects of secondary pollution, high cost, complex preparation process and the like since the performance of the vanadyl phosphatecatalyst is improved on the basis of noble metal are overcome. When the vanadyl phosphate catalyst is used for catalytic normal butane selectivity oxidation maleic anhydride reaction, the difficulties including low yield, poor selectivity and the like, are solved, and defects of high cost and serious pollution in a traditional catalyst improvement method are overcome.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI
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