The application discloses a composite additive for
electroplating copper of a
printed circuit board via hole and an
electroplating solution thereof, wherein the composite additive PPL-2000 is a
purine group with a
nitrogen-containing heterocyclic ring introduced in a
polyethylene glycol molecule with a molecular weight of 2000; on one hand, the introduction of the
purine group with the
nitrogen-containing heterocyclic ring not only significantly enhances the adsorption capacity of the
polyethylene glycol molecule to the
copper surface, but also makes the PPL-2000 molecule more easily enriched in a
high current density area, such as a surface protruding part and a via hole opening; on the other hand, the polyether functional group in the
polyethylene glycol molecule has a strong adsorption capacity and can be combined with Cl ‑ in the plating solution to generate a synergistic effect, so that a stable and dense adsorption structure is formed on the surface of the
copper layer, thereby effectively inhibiting the copper electrodeposition process.