The invention discloses a non-phosphorous low-carbon aluminum-magnesium non-fired brick for stainless steel ladles and a manufacturing method thereof, comprising high-bauxite of different particle levels, fused magnesia, corundum powder, spinel powder, alumina micropowder, silicon carbide Additives, wetting agents and phenolic resin binders, the mass percentage of each component is: 5-3mm high-bauxite 15-20%, 3-1mm high-bauxite 20-25%, ≤1mm high-bauxite 10-15%, 3-1mm fused magnesia 10-15%, ≤1mm fused magnesia 5-10%, corundum powder 10-15%, spinel powder 15-20%, ≤25μm alumina powder 2- 5%, silicon carbide additive 0.1-2%, wetting agent 0.1-2%, plus binder phenolic resin. Compared with the prior art, the outstanding advantage of the present invention is that it omits the firing process in the conventional method, saves energy, and does not contain phosphorus. Compression molding makes it have a higher density, avoids pollution to the stainless steel molten steel, and also has a higher service life.