The invention belongs to the technical field of
energy storage devices, and in particular relates to flexible water-based
sodium-
ion batteries and a preparation method thereof. The flexible water-based
sodium-
ion batteries take
sodium manganate as a positive active material and carbon-coated sodium-
titanium phosphate as a negative active material; the flexible water-based sodium-
ion batteries with excellent electrochemical performance are prepared from the
sodium manganate and the carbon-coated sodium-
titanium phosphate according to an appropriate
mass ratio; the two types of flexible water-based sodium-ion batteries are a two-dimension band-shaped flexible water-based sodium-ion battery and a one-dimensional thread-shaped flexible water-based sodium-ion battery. The band-shaped flexible water-based sodium-ion battery takes soft stainless steel as a
current collector; the thread-shaped water-based sodium-ion battery enables the active materials to be rolled into an orientation carbon
nano tube (CNT) to prepare composite fibers, and the CNT is used as a
current collector and a conductive additive at the same time, so that the
mass and volume of the battery are reduced, the flexibility of the battery is improved, and the thread-shaped water-based sodium-ion battery is easy to weave and integrate. The two-dimension band-shaped flexible water-based sodium-ion battery and the one-dimensional thread-shaped flexible water-based sodium-ion battery have excellent electrochemical performance, and have the advantages of being light in
mass, low in cost, high in flexibility and safety, environmental-friendly, and the like, thus providing possibility for the application in the field of wearable electronic devices. The thread-shaped flexible water-based sodium-ion battery can even be implanted in a
human body for assisting health monitoring and treatment of diseases.