A continuous annealing and acid washing method for medium-chromium ultrapure ferrite stainless steel comprises the process flow of cold rolling, annealing heat treatment, acid washing, final water washing, drying, flattening and packaging, and is characterized in that in the acid washing process flow, the acid washing solution is prepared from 120-150g / L of 65% nitric acid, 2-4g / L of 40% hydrofluoric acid and water. According to the invention, in the chemical acid washing stage, reasonable concentration ratio of nitric acid to hydrofluoric acid is adopted and proper acid washing speed is controlled to carry out acid washing on medium-chromium ferrite stainless steel. As a result, on one hand, the performance of a medium-chromium ferrite stainless steel passivation film is obviously improved, and the corrosion resistance of the surface of a medium-chromium ferrite stainless steel 2B board is significantly improved, and on the other hand, the process flow of the existing production factory is not needed to be changed, a special passivation treatment procedure is not needed, and the production cost is significantly lowered.