The invention provides a superaustenitic stainless steel electrode. A coating of the superaustenitic stainless steel electrode at least comprises the following components, by mass, 35 to 45 percent of rutile, 2 to 5 percent of titanium dioxide, 6 to 12 percent of marble, 6 to 12 percent of dolomite, 1 to 3 percent of quartz, 3.5 to 6.5 percent of cryolite, 4 to 8 percent of dehydrated feldspar, 3 to 5 percent of dehydrated phlogopite, 6 to 8 percent of chromium metal, 6 to 8 percent of electrolytic manganese, 3 to 6 percent of ferrotitanium, 1 to 2 percent of chromium oxide green, 2 to 4 percent of nickel powder, 0.5 to 1.5 percent of ferromolybdenum and 0.5 to 1.5 percent of sodium alginate. The coating of the superaustenitic stainless steel electrode is formed by mixing all the components according to the proportions, potassium and sodium are added to be mixed with sodium silicate, and the coating coats a core wire H02Cr20Ni25Mo4Cu to form the electrode. Carbon content is extremely low, comprehensive corrosion of sulfuric acid and phosphoric acid can be resisted, the corrosion of acetic acid at any temperature and in any concentration under ordinary pressure can be resisted, and an ideal welding material is provided for steel for manufacturing various strong acid storing and transporting containers.