The present invention belongs to the technical field of
polymer materials, and specifically relates to a
starch-based waterborne
polyurethane emulsion and its preparation method and application. The present invention mixes
glycerol and
polyethylene glycol, stirs and warms to 90-100°C, then adds
starch, stirs and warms to 120-140°C, keeps warm and stirs for 1-2h, then adds
methanesulfonic acid, stirs for 0.5-1h, cools to
room temperature, and obtains
starch-based polyols;
isophorone diisocyanate, 2,2-dihydroxymethylbutyric acid, and
solvent are mixed, stirred and warmed to 60-80°C, then a catalyst is added, stirred and reacted for 2-3h, then starch-based polyols are added, stirred and reacted for 2-3h, cooled to
room temperature after the reaction ends,
triethylamine is added, stirred and neutralized for 20-40min, then 3-aminopropyltriethoxysilane is added, stirred and reacted for 1-2h, then water is added, high-speed stirring and emulsification is performed for 1-2h, and the
solvent is removed by rotary
evaporation to obtain. The starch-based waterborne
polyurethane emulsion of the present invention has good stability and mechanical properties, and has good degradation ability, safety and
environmental protection.