The invention discloses a hexaaza-naphthyl
polymer, a preparation method thereof and an air self-charging
seawater-based battery. The structure of the
polymer electrode is shown as a formula I. According to the
polymer electrode, the
sulfonyl-connected hexaaza-naphthyl polymer is adopted as an active material of the
electrode, a large amount of space is provided, and meanwhile the
polymer electrode has good structural designability. On one hand, various cations in
seawater can be better accommodated, and on the other hand, the
electrolyte and the
electrode material can be further fully contacted, so that the resistance between phase interfaces is reduced, and the electrochemical performance is improved. The preparation method of the
sulfonyl-connected hexaaza-naphthyl
polymer electrode is simple and simple in process, and the whole preparation process does not involve the use of
metal. The Zn / / SHATN total battery disclosed by the invention shows excellent rate capability and excellent capacity
retention ratio, shows excellent self-charging performance in a
seawater-based
zinc salt
electrolyte, and also shows excellent self-charging performance in pure seawater.