The invention discloses a bismuth molybdate / titanium carbide heterojunction two-dimensional photocatalytic material as well as a preparation method and application thereof. The two-dimensional photocatalytic material includes titanium carbide nanosheets and layered bismuth molybdate supported on the titanium carbide nanosheets. The preparation method includes the following steps: preparing bulk titanium carbide; preparing the titanium carbide nanosheets by using dimethyl sulfoxide; and preparing the above two-dimensional photocatalytic material through a hydrothermal reaction. The two-dimensional photocatalytic material has the advantages of low costs, easy availability, low recombination efficiency of photoelectrons and holes, strong catalytic performance, good redox activity, and less harm to the environment, is a green and economic photocatalytic material, can be widely used to treat pollutants in the environment, and has higher use value and better application prospects; and the preparation method provided by the invention has the advantages of a simple process, convenient operation, low raw material costs, low energy consumption, short consumed time, mild easily controlled reaction conditions, greenness and environmental protection, and shows good application prospects in synthesis of functional nanomaterials.