176 results about "Vinylidene group" patented technology

An electronic device module comprising:A. At least one electronic device, e.g., a solar cell, andB. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) an ethylene-based polymer composition characterized by a Comonomer Distribution Constant greater than about 45, more preferably greater than 50, most preferably greater than 95, and as high as 400, preferably as high as 200, wherein the composition has less than 120 total unsaturation unit / 1,000,000C, preferably the ethylene-based polymer compositions comprise up to about 3 long chain branches / 1000 carbons, more preferably from about 0.01 to about 3 long chain branches / 1000 carbons; the ethylene-based polymer composition can have a ZSVR of at least 2; the ethylene-based polymer compositions can be further characterized by comprising less than 20 vinylidene unsaturation unit / 1,000,000C; the ethylene-based polymer compositions can have a bimodal molecular weight distribution (MWD) or a multi-modal MWD; the ethylene-based polymer compositions can have a comonomer distribution profile comprising a mono or bimodal distribution from 35° C. to 120° C., excluding purge; the ethylene-based polymer compositions can comprise a single DSC melting peak; the ethylene-based polymer compositions can comprise a weight average molecular weight (Mw) from about 17,000 to about 220,000, (2) optionally, a vinyl silane, (3) optionally, a free radical initiator, e.g., a peroxide or azo compound, or a photoinitiator, e.g., benzophenone, and (4) optionally, a co-agent.

Nonaqueous electrolytic liquids for lithium secondary batteries which have flame retardancy (self-extinguishing characteristics) or incombustibility (no flash point), have a high conductivity, and are electrochemically stable. One of the nonaqueous electrolytic liquids comprises a nonaqueous solvent comprising as an essential ingredient at least one phosphate (a) selected among chain phosphoric esters (a1) and cyclic phosphoric esters (a2). The nonaqueous solvent may further contain a cyclic carboxylic ester (b1) and a cyclic carbonic ester (b2). Another nonaqueous electrolytic liquid comprises the nonaqueous solvent and incorporated therein at least either a vinylene carbonate compound (c1) or a vinylethylene carbonate compound (c2) and one or more compounds selected from the group consisting of cyclic amide compounds (d1), cyclic carbamate compounds (d2), and cyclic hetero-compounds (d3).

An elastic laminate fabric useful for applications including apparel, sanitary products, and the like has an elastic vinylidene isoprene polymer film sandwiched between two outer non-woven layers. The laminate elastic fabric has CD elongation of at least 120%, and has recovery of at least 85% after several cycles of 100% elongation. A method of making the non-woven elastic laminate fabric includes extrusion coating a non-woven web having CD elongation of at least 120% with a vinylidene isoprene polymer film, and then thermocalendaring a second non-woven layer having a CD elongation of at least 120% to the exposed film surface. The mode of thermocalendering includes the use of an engraved calender roll having a discontinuous roll pattern and a land area no greater than 15%.

A fully formulated lubricating oil, lubricated surface, and lubricant additive concentrates for lubricants providing reduced sludge formation. The fully formulated lubricating oil composition has therein at least one succinimide dispersant derived from a polyalkylene compound having from about 50 to about 85% vinylidene double bonds in the compound, a metal containing detergent, at least one wear reducing agent, at least one antioxidant, and a hydrocarbon soluble titanium compound as a friction modifier. The lubricating oil composition is also substantially free of molybdenum compounds.

New and novel copolymers of vinylidene fluoride and hexafluoropropylene containing up to 24% by weight hexafluoropropylene having lower DSC melting temperatures at 8 weight percent or greater nominal HFP content, and having improved solution clarity and fluidity, longer gel times and lower extractables than prior art vinylidene fluoride-hexafluoropropylene copolymers of comparable HFP content whose syntheses are disclosed in sufficient detail to duplicate, to novel compositions of matter and articles of manufacture containing such copolymers, processes for the preparation and use of the copolymers, of the compositions of matter containing such copolymers and of the articles of manufacture containing such copolymers are disclosed. Improved electrochemical cells based on the new and novel copolymers are particularly disclosed.

The invention relates to a process for the purification of thiophenes by means of precipitation. The purified thiophenes are liquid at room temperature, have a purity of at least 99.50 wt. %, and are represented by the following general formula (I),wherein R1 and R2 independently of each other are, for example, a linear or branched C1-C20-alkyl group, or together form a fused C1-C20-dioxyalylene ring. The process involves: (I) precipitating the thiophene by cooling a solution of the thiophene and at least one solvent; or (II) precipitating the thiophene by adding the thiophene to a cooled solution of solvent and optionally the thiophene. The solutions are cooled to a temperature below the melting point of the thiophene.

Disclosed is a method for preparing polyolefins containing vinylidine end groups from quasiliving carbocationically terminated polyolefin polymers by contacting the quasiliving carbocationically terminated polymer with a suitable azole quenching agent and substituted derivatives thereof.

New and novel copolymers of vinylidene fluoride and hexafluoropropylene containing up to 24% by weight hexafluoropropylene having lower DSC melting temperatures at 8 weight percent or greater nominal HFP content, and having improved solution clarity and fluidity, longer gel times and lower extractables than prior art vinylidene fluoride-hexafluoropropylene copolymers of comparable HFP content whose syntheses are disclosed in sufficient detail to duplicate, to novel compositions of matter and articles of manufacture containing such copolymers, processes for the preparation and use of the copolymers, of the compositions of matter containing such copolymers and of the articles of manufacture containing such copolymers are disclosed. Improved electrochemical cells based on the new and novel copolymers are particularly disclosed.

The invention discloses a two-dimensional conjugated dibenzofuran conjugated polymer photoelectric material and a preparation method and application thereof. The polymer has a structural formula as shown in formula I, wherein A1, A2, R1 and R2 independently represent any one of the following groups: hydrogen, C1-C30 alkyl group, C1-C30 alkoxy group, cyan group, nitro group, ester group, aryl group, aralkyl group, halogen, alkylogen group, heteralkyl group, alkenyl group, and aryl group substituted by a substituent of a single bond, a double bond, a triple bond or combination thereof; Ar1, Ar2 and Ar independently represent any one of the following unsubstituted groups or groups containing a substituent: vinylidene group, ethynylene group, single ring arylene group, double ring arylene group, arylene group containing at least three rings, single ring heteroarylene group, double ring heteroarylene group, and conjugated units of heteroarylene group containing at least three rings, and n is a natural number between 5 and 500. The polymer material disclosed by the invention can be applied in the photoelectric field such as organic solar batteries and the high-mobility field effect tube field. (Formula I).

The present disclosure relates to a novel polyolefin having a terminal double bond and a method of producing the same. A polyolefin having a terminal double bond includes a polyolefin having a terminal double bond at either end and a polyolefin having a terminal double bond at one end, which are thermal degradation products of a polyolefin. An average number of terminal vinylidene groups per molecule is 1.3 to 1.9, a number average molecular weight (Mn) is 50,000 to 5,000,000, and a polydispersity index (Mw / Mn) of a molecular weight distribution is less than or equal to 5.0.

An ethylene copolymer is provided which is a copolymer of ethylene and an α-olefin of 3 to 20 carbon atoms and has the following properties:(a) the melt index (MI2) at 190° C. under a load of 2.16 kg is in the range of 0.0001 to 1000 g / 10 min,(b) the density is not more than 0.899 g / cm3,(c) the relationship between a vinyl group amount and MI2 of the polymer satisfies the following expression:(vinyl group amount: number of vinyl groups / 1000 carbon atoms)≦0.004509+0.000815×log(MI2),and(d) the relationship between a vinylidene group amount and MI2 of the polymer satisfies the following expression:(vinylidene group amount: number of vinylidene groups / 1000 carbon atoms)≦0.013528+0.002445×log(MI2).

Provided is a fin material for use with a heat exchanger. The surface of the provided fin material remains hydrophilic over a long period of time, and it is difficult for ice or frost to form on the provided fin material even if the temperature drops. Also provided is a resin composition that serves as a raw material for the aforementioned fin material, said resin composition being enduringly hydrophilic and exhibiting inhibition of ice and frost formation. Also provided is a laminated metal place on which an ice / frost-formation inhibition layer obtained from the aforementioned resin composition is formed. The aforementioned resin composition contains: (A) at least one anionic compound selected from a set comprising vinyl polymers, vinylidene polymers, polysaccharides, polyamino acids, and polypeptides, said compound(s) containing at least one anionic group selected from a set comprising carboxyl groups, sulfo groups, phosphate groups, and boric-acid groups; and (B) at least one cationic compound selected from a set comprising vinyl polymers, vinylidene polymers, polyalkylene imines, polyamines, polysaccharides, polyamino acids, and polypeptides, said compound(s) containing at least one cationic group selected from a set comprising amino groups, imino groups, amidine groups, pyridyl groups, imidazoline groups, and nucleobases.