The invention belongs to the technical field of interface agent, and discloses a composite polymer emulsion high-strength interface agent for a vitrified brick and a preparation method thereof. The interface agent comprises the following components by the mass fraction: 45-65% of a small-particle-size styrene-acrylic emulsion, 15-25% of a pure acrylic emulsion, 5-10% of a small-particle-size styrene-butadiene emulsion, 0.2-0.5% of a synergistic agent, 0.1-0.3% of a dispersant, 0.3-1.0% of a wetting agent, and the balance water. With adopting of the small-particle-size styrene-acrylic emulsion, with cooperation of the smaller-particle-size styrene-butadiene emulsion as a penetrating agent, and with collocation use of the water-based synergistic agent, the water solubility of the two kinds of emulsions are effectively improved, the compatibility of the emulsions is improved, the adhesion force and stability of an interface material are increased, the effect of penetrating into the back of a brick with low water absorption rate can be realized, the pulling strength of the material is also increased, the comprehensive effect of an acrylic emulsion is fully played, two-way permeability is achieved, and the adhesion force of a cement-based material is fully played.