54results about How to "Increase nucleation sites" patented technology

The invention discloses an economic-type pipe fitting steel with high strength and low yield ratio, which comprises the following elements: 0.10%-0.18% of C, 0.25%-0.55% of Si, 1.40%-1.90% of Mn, 0.02%-0.05% of Nb, 0.008%-0.020% of Ti, 0.02%-0.05% of V, 0.010%-0.040% of Als, smaller than or equal to 0.10% of Nb, V and Ti, 0-0.25% of Mo, 0-0.30% of Ni, 0-0.35% of Cu, 0-0.30% of Cr, smaller than or equal to 0.55% of Mo, Ni, Cu and Cr, and the balance of ferrum and unavoidable impurities. The yield strength after heat treatment can reach more than 630MPa or 690MPa, the tensile strength reaches more than 775MPa or 870MPa, the yield ratio is lower than 0.85, the impact ductility at minus 46 DEG C is not lower than 80J, and the technical requirements for X90 level and X100 level pipe fitting steel are completely satisfied.

The invention relates to a high strength hot rolled plate and a production process thereof, in particular to a heavy gauge hot rolled steel plate for a roll bending forming high strength steel plate pile and a production process thereof. The invention mainly solves the technical problems of inadequate thickness, and lowcold bending performance and absorbed-in-fracture energy in the prior high strength heavy gauge steel plate. The technical proposal comprises: the heavy gauge hot rolled steel plate for the roll bending forming high strength steel plate pile comprises the following chemical components by weight percentage: 0.08 to 0.15 percent of C, 0.10 to 0.40 percent of Si, 0.30 to 0.90 percent of Mn, 0.020 to 0.040 percent of Nb, 0.010 to 0.030 percent of Ti, less than or equal to 0.025 percent of P, less than or equal to 0.015 percent of S, and the balance being Fe. The microscopic structures can be fine grain ferrites, and pearlitic structures plus a small amount of bainite structures which are dispersed; the grain size level is 11 to 14; and the banded structure level is less than 0.5. The high strength hot rolled plate is mainly used for producing the steel plate pile.

The invention relates to a high-strength, low-yield-ratio, easy-to-weld mobile pressure vessel steel plate. The chemical composition of the steel plate is calculated by mass percentage, C: 0.14-0.20%, Si: 0.20-0.60%, Mn: 1.10-1.70%, P≤ 0.020%, S≤0.010%, Ni: 0.20~0.80%, Nb: 0.010~0.050%, V: 0.010~0.20%, 40ppm≤N≤80ppm, H≤2ppm, Pcm≤0.30, the balance is Fe and unavoidable of impurities. Manufacturing process: converter smelting→ladle furnace refining→vacuum treatment→continuous casting→slab heating→controlled rolling→controlled cooling→slow cooling→flaw detection→normalizing→performance inspection. The present invention adopts design concepts such as solid solution strengthening, fine grain strengthening and toughening, and the steel plate is delivered in a normalized state, integrating high strength, high toughness, low yield ratio, and excellent welding performance. It has excellent performance and short production cycle. Features such as low cost.

The invention discloses economical low-yield-ratio steel for pipe fittings for oil and gas transmission and a method for producing the economical low-yield-ratio steel. The economical low-yield-ratio steel comprises from 0.09% to 0.16% of C, from 0.20% to 0.40% of Si, from 1.00% to 1.39% of Mn, from 0.01% to 0.04% of Nb, from 0.005% to 0.018% of Ti, from 0.01% to 0.04% of V, from 0.008% to 0.035% of Als, from 0% to 0.20% of Mo, from 0% to 0.30% of Ni, from 0% to 0.30% of Cu, from 0% to 0.25% of Cr, the balance iron and inevitable impurities, wherein the total content of the Nb, the V and the Ti is lower than or equal to 0.09%, and the total content of the Mo, the Ni, the Cu and the Cr is lower than or equal to 0.40%. After the economical low-yield-ratio steel is subjected to heat treatment, the yield strength of the economical low-yield-ratio steel for the pipe fittings can be higher than 490MPa or 560MPa, the tensile strength of the economical low-yield-ratio steel can be higher than 670MPa or 720MPa, the yield ratio of the economical low-yield-ratio steel is lower than 0.80, the impact toughness of the economical low-yield-ratio steel at the temperature of minus 46 Celsius degrees is not lower than 80J, and technical requirements of X70-grade steel for pipe fittings and X80-grade steel for pipe fittings are met completely.

The invention provides a TiAl alloy crystal grain refinement method. Through cyclic treatment in a solid-liquid two-phase region, a bulky columnar crystal undergoes remelting, a fused dendritic crystal can be used as a new nucleation particle which undergoes nucleation and growth, so a crystal grain is refined. According to the invention, treatment is carried out on a peritectic solidification path with a Ti48Al2Cr2Nb alloy as a representative, an alpha solidification path with a Ti50Al alloy as a representative and a beta solidification path with a Ti45Al8Nb0.2W0.2B alloy as a representative, and a substantial refinement effect is obtained; the method has the characteristics of a wide application scope and suitability for crystal grain refinement of a plurality of TiAl alloys.

The invention relates to a method for preparing a super-hydrophilic and hydrophobic composite nano array interface material, which comprises the following steps: 1)taking a copper sheet as a base material, preparing a zinc oxide nano conical fascia by a chemical bath sedimentation method in hot bath; 2)using seventeen perfluorinated silane for modifying the oxidative nano conical fascia at 120 DEG C by a vapour deposition method; 3)preparing a polyvinyl alcohol low-solid content aqueous solution; 4)establishing an ultrasonic atomization and condensation platform, atomizing the polyvinyl alcohol aqueous solution with concentration being 0.1-0.2%, reducing the temperature of the surface of the copper-based zinc oxide nano conical fascia to 1-5 DEG C through the condensation platform, uniformly condensing the surface of the super-hydrophobic zinc oxide nano conical fascia by the polyvinyl alcohol dispersion liquid dispersed in air, performing spray deposition under observation of a high power CCD imaging system; and 5)rapidly transferring to a constant temperature heating stage, solidifying at constant temperature, after solvent moisture is completely volatilized, solidifying polyvinyl alcohol and absorbing on the surface of the zinc oxide nano conical fascia to form a hydrophilic and hydrophobic composite nano array interface. The method has the advantages of simple process and low cost, and the material has high anti-condensation frosting performance.

The invention provides a high-strength and high-conductivity copper magnesium alloy contact wire. The contact wire comprises the following components of, by weight, 0.1%-0.8% of magnesium, 0.1%-0.4% of nickel, 0.1%-0.4% of zinc, 0.1%-0.4% of silver, and the balance copper and inevitable impurity elements. The prepared high-strength and high-conductivity copper magnesium alloy contact wire has excellent comprehensive performance, solves the technical problem that in the prior art, consideration cannot be given to electric conductivity and tensile strength of a copper magnesium alloy at the same time, and can meet the requirement for the performance of the copper alloy for railway contact wires.

The invention relates to a wide-width, high-strength, high-toughness and thick-wall X80M pipeline steel plate and a manufacturing method thereof. The steel plate is prepared from the chemical components including, by weight, 0.045%-0.08% of C, 0.20%-0.38% of Si, 1.55%-1.85% of Mn, 0.15%-0.35% of Cu, less than or equal to 0.010% of P, less than or equal to 0.015% of S, 0.04%-0.08% of Nb, 0.015%-0.028% of Ti, 0.015%-0.045% of Al, 0.25%-0.5% of Cr, 0.004%-0.006% of N, 0.032%-0.06% of V, 0.03%-0.05% of Zr, less than or equal to 0.15% of Ni, less than or equal to 0.12% of Mo, 0.0012%-0.0035% of Ca and the balance Fe and inevitable impurities. The produced steel plate has the comprehensive performance of high strength and good low-temperature toughness, and can ensure the safety of oil and gas transmission pipelines.

The invention relates to a method for producing Nb-containing high-speed train wheel steel, and belongs to the field of metal materials. The wheel steel comprises the following components in percentage by weight: 0.40 to 0.70 percent of C, 0.70 to 0.80 percent of Mn, 0.30 to 0.60 percent of Si, 0.015 to 0.110 percent of Nb, 0.20 to 0.35 percent of Cr, less than or equal to 0.020 percent of P, less than or equal to 0.015 percent of S and the balance of Fe and inevitable elements. The method comprises the following steps of: smelting, forging to obtain a steel billet, performing normalization and heat preservation at the temperature of between 850 and 900 DEG C for 1 hour, performing air cooling or water spray cooling to room temperature, and ensuring that cooling speed is controlled in therange of 1 to 15 DEG C/s and a room temperature structure is ferrite and pearlite. The high-speed train wheel steel produced by the method has the tensile strength of 740 to 900MPa, the yield strength of 450 to 570MPa, the breaking elongation of 15 to 25 percent and the low temperature (-20 DEG C) impact work (Akv) of 15 to 20J, and a uniform structure with 10 to 25 percent of ferrite can be obtained at room temperature. The Nb-containing high-speed train wheel steel has mechanical properties of high strength and toughness, and overcomes the defect of a low toughness value of the conventionalhigh and medium carbon wheel steel.

A method of forming an Si—Ge epitaxial layer comprising the following steps. A structure is provided and a doped Si—Ge seed layer is formed thereover. The doped Si—Ge seed layer having increased nucleation sites. A Si—Ge epitaxial layer upon the doped Si—Ge seed layer whereby the Si—Ge epitaxial layer lacks discontinuity.

The invention relates to high-carbon high-chromium martensitic stainless steel for a cutter and a preparation method thereof, and belongs to the technical field of materials. The high-carbon high-chromium martensitic stainless steel comprises the following chemical components of, in percentage by weight, 0.90%-1.20% of C, 14.0%-16.0% of Cr, 1.0%-2.0% of Co, 0.5%-1.5% of Mo, 0.20%-0.40% of V, 0.2%-0.6% of Mn, 0.001%-0.01% of La, less than 0.01% of P, less than 0.01% of S and the balance iron. The preparation method of the high-carbon high-chromium martensitic stainless steel comprises the following steps of burdening, smelting, casting molding, forging and hot working, cold working and heat treatment. According to the high-carbon high-chromium martensitic stainless steel for cutter and thepreparation method thereof, the rare earth element content in the material is optimized, primary carbide coarsening is inhibited, carbide uniform distribution is promoted, the heat treatment process is improved, the martensite content and the austenite content in a matrix are controlled, and the optimal matching of the strength and the toughness of the material is obtained.

The invention belongs to the field of an electrochemical energy storage material, and relates to a nano barium sulfate/carbon composite material and a preparation method and an application therefor. According to the nano barium sulfate/carbon composite material, the nano barium sulfate is distributed on the surface of the carbon material, and is in full contact with the surface of a lead plaster active material for providing a large amount of crystal nucleus for lead sulfate crystalline grain deposition; meanwhile, carbon combined with active locations of barium sulfate can transfer electrons, so that the conductivity in the reaction points is reinforced; and in addition, the preparation method for the nano barium sulfate/carbon composite material is simple in method, short in period, free of pollution, and high in advantages used in industrial production. A negative electrode material prepared by taking the nano barium sulfate/carbon composite material provided by the invention as one of the raw materials is excellent in the charge-discharge performance; the negative electrode sulfation phenomenon can be reduced; and the capacity retention ratio of the negative electrode material is still kept more than 90% after the negative electrode material is subjected to 2,000 charge-discharge circles at current of 1C for charge and at current of 0.3C for discharge, so that the advantage of high cost performance is achieved.

The invention discloses a method for depositing a perovskite film on a hydrophobic hole transport layer. A high-quality perovskite film is prepared by using a hole transport layer modified by a polyvinylpyrrolidone (PVP) interface. A PVC interface modification layer can be introduced between the hole transport layer and the perovskite film to prepare the perovskite film with high smoothness and high fluorescence yield. Compared with the perovskite film prepared by the traditional method without PVC modification, the surface roughness of the film modified by the PVC interface is reduced, and the fluorescence yield is enhanced. In the method disclosed by the invention, the interface of HTL is modified by PVP, the pyrrolidone portion in the PVP has good hydrophilicity, so that the wettabilityof a perovskite precursor to the HTL is greatly improved, the nucleation site of the perovskite is improved, and smooth and flat perovskite films can be prepared.

The invention discloses a high heat input welded high-intensity hot-rolled steel bar which comprises 0.27-0.29 percent of C, 0.15-0.17 percent of Si, 1.11-1.13 percent of Mn, 0.007-0.009 percent of P, 0.001-0.003 percent of S, 0.057-0.059 percent of Als, 0.005-0.007 percent of Nb, 0.06-0.08 percent of V, 0.035-0.037 percent of Ti, 0.05-0.07 percent of Ni, 0.07-0.09 percent of Cu, 0.6-0.8 percent of Cr, 0.53-0.55 percent of Mo, 0.007-0.009 percent of B, 0.07-0.09 percent of lanthanum, 0.03-0.05 percent of cerium, 0.01-0.03 percent of praseodymium and the balance of Fe. According to the high heat input welded high-intensity hot-rolled steel bar, the intensity of the steel bar and the toughness of a welding heat affecting region can be effectively improved.

The invention provides a low alloy weathering steel. The low alloy weathering steel contains chemical components by following weight percentage: 0..02-0.05% of C, 0.6-1% of Mn, 0.2-0.4% of Cu, 15-0.5% of Ni, 0.04-0.07% of Nb, 0.005-0.015% of Ti, 0.3-0.6% of Si, <= 0.02% of Al, <=0.02% of P, <=0.08% of S and the balance of Fe and inevitable impurities. The low alloy weathering steel reduces usage amount of the high cost alloy elements of Cr and Ni by improving content of the low cost alloy element of Si, and adopts synergistic effects among the alloy elements to reduce usage of the high cost alloy elements and achieve maximization of cost effectiveness. Simultaneously, the low alloy weathering steel has good comprehensive mechanical properties, and is suitable for application requirements of bridges and the like under industrial marine atmospheric environment.

The invention provides curing liquid applicable to calcium phosphate-based bone cement as well as a preparation method and application of the curing liquid. The curing liquid applicable to the calciumphosphate-based bone cement comprises the following components by mass percentage: 2-9% of citric acid, 1-6% of PVP, 5-25% of phosphate and 1-5% of PVA. The invention creatively utilizes the abilityof phosphate to promote early hydration products; an acidic environment is provided by citric acid; PVP has a molecular mediated effect on calcium phosphate deposition; PVA has a water-retaining function; through the synergistic effect of citric acid, phosphate, PVP and PVA, the mechanical properties of calcium phosphate bone cement such as curing ability, early strength, late strength and the like are significantly improved, the medical value of calcium phosphate bone cement is expanded, at the same time, calcium phosphate bone cement is closer to clinical use standards, and calcium phosphatebone cement has broad application prospects.

The invention discloses a method for improving the room-temperature tensile property of a Ti-48Al-2Cr-2Nb alloy through adding of nano Y2O3, and belongs to the field of room-temperature mechanical properties of metal materials. The method for improving the room-temperature tensile property of the Ti-48Al-2Cr-2Nb alloy through adding of the nano Y2O3 aims at solving the problem that an existing directly-casted Ti-48Al-2Cr-2Nb alloy is coarse in structure, and serious in segregation. The method comprises the steps that nano Y2O3 particles are added in the Ti-48Al-2Cr-2Nb alloy, a water cooled copper crucible is adopted to induce a solidification shell smelting furnace, and under the high-vacuum/argon environment, through the melt reaction, a full-lamellar structure with the fine Y2O3 particles evenly distributed in a dispersed manner is directly generated. After the nano Y2O3 is added, the room-temperature tensile strength of the alloy is obviously improved, and the room-temperature plasticity of the alloy is greatly improved.

The invention discloses an electrode coating as well as a preparation method and an application thereof. According to a coating formed by the coating, the uniformity of zinc deposition is adjusted byusing a cheap nano dielectric filler, on one hand, transmission of zinc ions can be adjusted by a nano channel formed by nano particles, and on the other hand, nucleation sites of zinc on an electrodecan be increased, so that dendritic-crystal-free zinc deposition is realized. Meanwhile, water molecules in an electrolyte can be effectively isolated under the barrier action of dipoles generated bythe coating containing the high-dielectric-constant nano filler and physics, so that corrosion and hydrogen evolution reaction on the zinc negative electrode are inhibited, and the stability of the zinc negative electrode can be remarkably improved. A coating layer formed by the coating is large in dielectric filler proportion, dipole-dipole effect produced by the dielectric filler can be used, distribution of zinc ions relative to the surface of an electrode can be adjusted through the electrostatic interaction of dipoles and the zinc ions, the tip electric field enhancement effect is weakened, nucleation sites on the surface of the electrode are increased, and therefore dendritic crystals are effectively restrained from being generated.

The invention provides a casting method of an aluminum alloy cast rod. Chemical composition elements of the aluminum alloy cast rod and the structure of a crystallizer are optimized so that when the aluminum alloy cast rod is cast, a temperature adjusting device, the stirring speed and the stirring time can be more accurately controlled through a controller, formability of aluminum alloy melt is guaranteed, meanwhile, uniformity of the internal temperature of the aluminum alloy melt can be guaranteed, the situation that an aluminum alloy dendritic crystal arm is broken into dendritic crystal fragments is effectively reduced, nucleation positions are added, more non-uniform nucleation occurs, the grain refining effect is remarkably generated, then the tendency that cracks are generated on the cast rod is reduced, the casting smelting quality is improved, and the yield is increased. The problems that when a large-size and large-diameter aluminum alloy cast rod is cast, the temperature of aluminum alloy melt is not uniform due to the high casting temperature, consequently, the cooling speeds and the cooling degrees of all parts of the cast rod are different, the cracking tendency exists, and cracks are generated in the cast rod are effectively solved.

The invention provides Ca-containing low-alloy weathering-resistant steel. Chemical ingredients of the Ca-containing low-alloy weathering-resistant steel include, by mass, 0.02%-0.05% of C, 0.20%-0.30% of Si, 0.6%-1.00% of Mn, 0.005%-0.010% of Ti, 0.0005%-0.0020% of Ca, 0.20%-0.40% of Cu, 0.20%-0.60% of Ni, 0.04%-0.07% of Nb, not larger than 0.02% of P, not larger than 0.08% of S, not larger than 0.02% of Al and the balance Fe and inevitable impurities. The size and distribution of inclusions in the steel can be changed by adding the appropriate amount of Ca, the tiny inclusions in the steel are easily generated and are evenly dispersed and distributed, the structure of the steel can be more uniform, the strength of the steel is improved, the weathering resistance of the steel can be effectively improved by using the Ca and other elements such as Si and Cu in cooperation, the weathering resistance of the steel under the natural condition is improved, and the corrosion-resistant performance of the steel is improved.

The invention discloses a room temperature NO2 sensor based on in-situ growth nano In2O3 on the surface of a non-metal mineral electrode substrate and a preparation method, which belong to the field of gas sensors of metal oxide semiconductor materials. According to the invention, a non-metal mineral porous ceramic electrode is used as a substrate; a direct current sputtering method is used to sputter an interdigital electrode on the surface of the substrate, and the In2O3 nano material hydrothermally grows in situ on the surface thereof; the In2O3 nano material is in a rod-like structure and uniformly and densely distributed on the surface of the substrate, wherein the diameter thereof is 120 to 200nm and the length thereof 0.5 to 1 micron; the rod-like structure is composed of nanoparticles stacked on each other; the nanoparticles are in the structure of In2O3 cubic phase crystals, and the diameter thereof is 10 to 30 nm. The gas sensor can have a fast response and recovery rate for 0.1 to 1 ppm NO2 under room temperature working conditions and under UV light assisted recovery, and has the advantages of excellent selectivity, long-term stability and good application prospects.

The invention discloses a polyurethane modified carbon nanotube/PLA/PBAT composite material containing a sulfonic acid ionic liquid element. The raw material formula of the composite material comprises 0.4-2% of polyurethane containing the sulfonic acid ionic liquid element, 36-57% of PLA, 36-57% of PBAT and 6-8% of a carbon nanotube. In the invention, the interface of the PLA and the PBAT is compatibilized by the polyurethane containing the sulfonic acid ionic liquid element so as to improve the compatibility, the PBAT plays a role in toughening the PLA so as to enhance the mechanical property of the composite material, and meanwhile, an imidazole group in the polyurethane containing the ionic liquid element can promote the dispersion compatibility of the carbon nanotubes and improve the electromagnetic shielding property of the composite material; and the composite material has good electromagnetic shielding performance and mechanical property, is environment-friendly and easy to process, and has excellent practical value.