The invention provides a method for preparing a super-microporous
polymer material without surface gas traces. The method comprises the following steps: (1) synthesizing
polymer nano core-shell particles by adopting a one-step
emulsion polymerization method, wherein microspheres are in a core-shell structure and have the sizes in the range of 80-400nm, the structure is uniform, and the shell layer has a chemical cross-linking structure; and (2) compounding the core-shell particles and a
polymer matrix through a
melt blending or in-situ
polymerization method, wherein the material has a closed pore structure. According to the super-microporous polymer material prepared by adopting the process, the porous size distribution ranges from 100 to 400nm, the number of pores in
unit volume reaches 10<12> cells / cm<3>, and the polymer material has typical microporous polymer structural characteristics. According to the method, gas
diffusion can be effectively limited, and gas traces on the material surface are avoided; the
processing process is simple, fast and economic, the
processing window is wide, and the pore structure is easily controlled; and
high pressure and
high pressure drop rate are not needed, the cost can be reduced, and the production efficiency is improved; molding is performed through a traditional polymer
processing method, special equipment is not needed, and the cost is low.