The invention provides a method for catalytic oxidation of dioxin-like pollutants in waste incinerators, hazardous waste incinerators, medical waste incinerators, steel sintering furnaces, coal-fired power plants, funeral homes and chemical plant flue gas and exhaust gases. Eliminated catalysts and methods of preparation. The catalyst is supported by industrial titanium dioxide, SnO 2 -V 2 o 5 -WO 3 Composite oxide is the active component, La 2 o 3 、MoO 3 , CeO 2 , Nb 2 o 5 , CuO, Pr 6 o 11 and Sb 2 o 3 as an auxiliary agent. In the catalyst prepared by the present invention, the active components are uniformly dispersed on the surface of the carrier under the complexation of organic amines, and the catalyst auxiliary agent is uniformly precipitated on the surface of the carrier under the condition of ammonia water, so that the catalyst has a high specific surface area, high thermal stability and comparative Strong anti-chlorine poisoning ability, continuous long-term operation without activation, low operating temperature in the elimination of dioxin-like pollutants, and high dioxin decomposition efficiency.