The invention relates to a treatment method of electrolytic
manganese metal waste residues. The treatment method comprises the following steps: A,
grinding gypsum or
drying calcined
gypsum and then
grinding to obtain
gypsum powder; B, slurrying the electrolytic
manganese metal waste residues, leaching, and adding the gypsum
powder; adjusting the pH of a solution to 6.0-6.4, removing iron, carryingout filter pressing to obtain a filter pressing block A and a filter pressing solution A, washing the filter pressing block A with water, and then carrying out filter pressing to obtain a filter pressing block B and a filter pressing solution B; adjusting the pH of the filter pressing solution A to 11.5-12, and carrying out filter pressing to obtain a filter pressing block C and a filter pressingsolution C; C, adding
silicon dioxide,
calcium oxide, aluminum
oxide and
iron oxide into the filter pressing block B,
drying, pre-decomposing, and calcining to obtain
cement clinker; D, slurrying thefilter pressing block C, leaching, adjusting the pH to 6.0-6.4, removing impurities, standing, and carrying out filter pressing to obtain a filter pressing block D and a filter pressing solution D, adding
ammonia water into the filter pressing solution D to adjust the pH to 8.8-9, and continuously adding an
ammonia water solution to adjust the pH to 11.4-11.8. The method realizes recycling of resources.