The present invention relates to a process for preparing ozone through a low pressure electrolytic method. In an electrolytic tank of diaphragm type or non-diaphragm type, a neutral or acidic electrolysing solution is added, a non-corrodible steel electrode, a nickel alloy electrode, a lead alloy electrode or a graphitic electrode is selected as the cathode, a fluorine-containing lead dioxide electrode is selected as the anode, an electric current density of 100-2000 A/m2 and a tank voltage of 3.0-6.0 V are adopted, and the temperature of the electrolysing solution is controlled at 5-35 DEG C, then ozone is obtained after energization for an electroanalysis. The substrate of said fluorine-containing lead dioxide electrode is titanium, graphite or ceramics. Said ozone generating device for preparing ozone in accordance with the present invention is characterized by its simple structure, convenient operations, superior performances, capability of operations at normal temperature and pressure, low energy consumption, high ozone concentration generated, and avoidance to generate oxynitrides harmful to persons and entironment during electrolysises, and then is a green environmental protection equipment. According to actual needs, said method is capable of being extensively used for generating ozone in fields such as disinfection, sterilization, odor treatment, fresh-keeping, air purification, preparation of pure water, wastewater treatment, organic synthesis and the like.