The invention relates to a
cathode material of a
solid oxide fuel
cell, in particular to an A omission Ba1-z(Co1-x-yFexMy)O3-
delta(BCFM, x=0 to 0.9, y=0.1 to 0.5, and z=0.01 to 0.3)
perovskite cathode material and application thereof, wherein M is Zr, V, Nb, Ti, W, Mo, Ta or Hf. The invention is characterized in that the Ba omission in introduced in
a site A on
titanium ore type BaCo1-xFexO3-
delta(BCF) materials, high-valence ions are doped in
a site B, the
cobalt content is reduced, and the molecular formula is Ba1-z(Co1-x-yFexMy)O3-
delta. The porous A omission site B high-valence
doping perovskite materials prepared by the invention have the advantages of good thermal and
chemical stability and
high oxygen catalytic activity, and can effectively reduce the
cathodic polarization. The BCFM materials singly form an SOFC
cathode or form the SOFC cathode with
electrolyte materials through being compounded. The cathode is in a nano-
micro structure with two
layers, wherein the outer layer is in a large-grain loose structure, and the inner layer is in a fine-grain relatively compact structure. The BCFM cathode can be used as the SOFC cathodes with different structures and compositions. The output power of the
cell at 650 to 700 DEG C is about 1.0 W / cm<2>.