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30results about How to "Strong resistance to electrochemical corrosion" patented technology

Modified inorganic lithium silicate binder, and preparation method and use thereof

The invention relates to a modified inorganic lithium silicate binder, and in particular relates to a water-based binder containing lithium silicate, silica soil and auxiliaries. More specifically, the modified inorganic lithium silicate binder comprises 10-25 parts of lithium silicate, 60-75 parts of silica soil and 10-15 parts of modified binder and 0.6-3 parts of auxiliaries, wherein the lithium silicate is prepared from 3-10 parts of de-ionized water, 0.5-1.5 parts of lithium hydrate, 5-12 parts of silica soil and 1-2 parts of stabilizer through a reaction; the modified binder is organic fluorine and / or an organic silicon modified acrylic emulsion. The binder provided by the invention is environment-friendly and free of pollution; the content of SiO2 of the modified inorganic lithium silicate binder does not exceed 20%; and the binder is low in viscosity, short in drying time; as a result, the formed dry film is insoluble in water, and excellent in bonding strength, flexibility and impact resistance; the binder is used for preparing an anticorrosion water-based inorganic zinc rich paint, and the combination properties of the paint film are improved; especially, the paint film is excellent in corrosion resistance, high in bonding strength, tough and wear resistant, and also excellent in crazing resistance, oil resistance, organic solvent resistance, weather fastness and high / low temperature resistance; the paint film has the welding performance with paint and has a function of protecting steel structures against corrosion for a long time.
Owner:JIUQING PAINT SHANGHAI

Anti-corrosion conductive ceramic electrode material for sewage and sludge treatment and preparation method thereof

ActiveCN105523761AGood for anodizingUnique electrochemical performanceWater/sewage treatment by electrochemical methodsElectrochemical sludge treatmentFiberEpoxy
The invention discloses an anti-corrosion conductive ceramic electrode material for sewage and sludge treatment and a preparation method of the anti-corrosion conductive ceramic electrode material. The anti-corrosion conductive ceramic electrode material is characterized in that carbon is used as aggregate; the anti-corrosion conductive ceramic electrode material is prepared from artificial graphite, graphitized mesocarbon microbeads, a reinforcement binder, graphitized carbon fiber and E-44 epoxy resin. The preparation method comprises the following steps of adding a Ti4O7 functional additive having strong electrode performance, simultaneously adding one or several of ceramic anti-wear-corrosion components of TiB2, TiO2, TiC, B2O3, SiO2 and SiC, carrying out solidification, compression molding and high-temperature sintering after adding a mixing solvent and completely mixing the mixture, and finally preparing the anti-corrosion conductive ceramic electrode material. According to the anti-corrosion conductive ceramic electrode material and the preparation method, disclosed by the invention, aiming at an actual working situation of a sewage and sludge treatment environment, unique anti-corrosion components are added while low specific resistance of the anti-corrosion conductive ceramic electrode material is ensured, not only are wearing resistance and corrosion resistance of traditional ceramics obtained, but also excellent conductivity and excellent electrochemical performance are obtained, and the service life is up to more than 3500 hours.
Owner:JIANGSU UNITED CERALLOY MATERIALS TECH

Porous membrane with nanometer aperture and preparation method thereof

The invention discloses a porous membrane with nanometer aperture and a preparation method thereof. The preparation method comprises the following steps of: (1) dissolving a polymerization monomer containing hydrophilic radical groups and double bonds and polyvinylidene fluoride in an organic solvent, so as to obtain a casting film solution; (2) carrying out curtain coating on the casting film solution by using a casting film method to form a thin film; (3) carrying out polymerization reaction on the polymerization monomer inside the thin film to generate low-molecule polymers, so that the organic solvent inside the thin film is evaporated and removed; and further arranging the thin film in an outer electric field, so that the polymerization monomer is subjected to the polymerization reaction under the effect of the outer electric filed; and (4) placing the thin film processed in the step (3) for impregnation in a water solution, and removing all the low-molecule polymers, so as to obtain the porous membrane with the nanometer aperture. The porous membrane with the nanometer aperture is suitably used as a membrane in an electric chemical device, and further can be used in a separation process and a matter conversion process under the driving of the electric field. With the adoption of the preparation method provided by the invention, the complicated processes of normally using a sulfonating agent in the conventional preparation ion conduction film, executing a plurality of preparation steps and the like can be avoided. The preparation method is simple, and the industrial amplification production can be easily realized.
Owner:TSINGHUA UNIV

Method for preparing organic acid by electrolyzing organic acid salt on basis of chlor-alkali perfluor ion exchange membrane

The invention relates to a method for preparing an organic acid by electrolyzing an organic acid salt on the basis of a chlor-alkali perfluor ion exchange membrane. According to the method, an electrolytic bath which is equipped with a perfluor ion exchange membrane between electrodes and is mainly composed of an anode chamber, an anode, the perfluor ion exchange membrane, a cathode and a cathode chamber is adopted. The method comprises the following steps: respectively supplying an anode solution and a cathode solution to the anode chamber and the cathode chamber of the electrolytic bath and performing electrochemical ion exchange, wherein the anode solution is an aqueous solution of the organic acid salt and the cathode solution is an alkali solution corresponding to cations in the organic acid salt; applying a direct current to the electrolytic bath so as to perform constant current electrolysis, and combining the anions in the organic acid salt solution enriched in the anode chamber with hydrogen ions generated by the anode chamber, thereby generating the organic acid; and collecting discharged solution containing the organic acid enriched in the anode chamber, concentrating and crystallizing, thereby obtaining the high-purity organic acid. The method has the advantages of simple process, easiness in industrial amplification, high current efficiency, and the like, and can realize the industrial preparation for the high-purity organic acid.
Owner:SHANDONG DONGYUE POLYMER MATERIAL

Strain clamp for aluminum alloy core aluminum stranded wire

The invention provides a strain clamp for an aluminum alloy core aluminum stranded wire. The strain clamp comprises a drainage plate 6, a drainage wire clip 7 which is connected with the drainage plate 6, a strain steel anchor 3, and an aluminum alloy tube 4 and a strain aluminum 5 which are orderly sleeved outside the strain steel anchor 3. Sleeve crimped parts are an anchor head 31 and a middle connecting part 32 of the strain steel anchor 3. One end which is not crimped of the aluminum alloy tube 4 is contained with a cavity for containing an inner core 1 of the aluminum alloy core aluminum stranded wire. One end which is not crimped of the strain aluminum 5 is provided with a cavity for containing a stranded wire 2. The middle part of the strain aluminum 5 is provided with the drainage plate 6. The aluminum alloy core aluminum stranded wire, the strain steel anchor 3, the aluminum alloy tube 4 and the strain aluminum 5 are coaxially arranged. The strain steel anchor 3 and the aluminum alloy tube 4 are pressed in advance. According to the strain clamp, mature hydraulic technology pressing is employed, the strain steel anchor and the aluminum alloy tube are pressed in a factory, the field construction is reduced, parts are few, an operation is convenient, the pressing quality is easy to be ensured, the corrosion resistance performance is good, high quality materials are selected, the installation is simple, the construction is facilitated, mechanical properties and electrical properties are good, and the quality is stable.
Owner:STATE GRID CORP OF CHINA +2

Manufacturing method of light edge controllable electrode foil for solid aluminum electrolytic capacitor

The invention relates to a method for manufacturing a light edge controllable electrode foil for a solid aluminum electrolytic capacitor. The method comprises the following steps of: performing oil removal operation on the surface of an aluminum foil; performing local coating operation on the aluminum foil; performing curing treatment on the coating layer; performing electrochemical corrosion operation on the aluminum foil; the aluminum foil is placed in pure water to be washed; the aluminum foil is placed in a chemical cleaning solution to be subjected to post-treatment cleaning; and finally carrying out post-processing operation on the aluminum foil. Therefore, on one hand, the electrochemical corrosion process of the aluminum foil has definite directivity and controllability, and it is ensured that the formed corrosion foil has good mechanical strength; and on the other hand, no matter under any electrochemical corrosion condition, the'smooth edge 'on the aluminum foil can be prevented from being corroded, a good foundation is laid for reducing the width of the'smooth edge' as much as possible, the phenomenon that a large amount of aluminum foil raw materials are wasted is effectively eliminated, and the possibility is provided for more thorough corrosion of a non-coating area of the aluminum foil.
Owner:NANTONG HAIXING ELECTRONICS +2

Preparation method of liquid flow battery composite material bipolar plate

The invention relates to a preparation method of a liquid flow battery composite material bipolar plate, belonging to the technical field of liquid flow battery bipolar plate preparation. The preparation method of the liquid flow battery bipolar plate comprises three steps of using a solution method for mixing, using a tape casting method for casting and using a compression molding method for molding successively. The weight percentage of graphite powder / (graphite powder plus polyvinylidene fluoride) is 30% to 75%, and the dissolving temperature is 50 DEG C to 110 DEG C. The thin-layer thickness of a solution casted by the tape casting method is 0.2mm to 5mm, the compression molding temperature is 190 DEG C to 250 DEG C, and the pressure is 11MPa to 30MPa. The composite material bipolar plate made by using the method has the thickness of 1.0mm to 2.2mm and the electrical conductivity of 0.13S / cm to 41S / cm. The invention is easy for organizing large-scale and low-cost production processso as to overcome the shortcomings of complex processing and poor electrical conductivity of the prior liquid flow battery bipolar plate, thus laying the foundation for developing the chemical powertechnology used in large-scale energy conversion and storage.
Owner:TSINGHUA UNIV

Method for preparing high-purity peroxysulphate based on electrolytic oxidation through ion-exchange membrane electrolyzer for chlor-alkali production

The invention relates to a method for preparing high-purity peroxysulphate based on electrolytic oxidation through an ion-exchange membrane electrolyzer for chlor-alkali production. According to the method, a perfluorinated ion exchange membrane is arranged between electrodes, and the electrolyzer comprises an anode compartment, an anode, the perfluorinated ion exchange membrane, a cathode and a cathode compartment. The method comprises the following steps: an anolyte sulfate aqueous solution and a catholyte alkali solution are respectively supplied to the anode compartment and the cathode compartment of the electrolyzer to conduct electrochemical ion exchange, the electrolyzer is charged with direct current to conduct constant current electrolysis, sulphate ions in the sulphate solution are enriched in the anode compartment because of not passing through the ion-exchange membrane, and are migrated on the anode in the anode direction to discharge to generate sulfate radicals, the sulfate radicals are combined with M<+> to generate sulfate, and the anode out-of-electrolyzer solution is subjected to after treatment to obtain high-purity peroxysulphate. The method overcomes the defects that in the prior art, the energy consumption is high, and the current efficiency is low, is simple in process, achieves high current efficiency and low energy consumption, and is easy to realize industrial production.
Owner:SHANDONG DONGYUE POLYMER MATERIAL

Method for preparing organic acid by electrolyzing organic acid salt on basis of chlor-alkali perfluor ion exchange membrane

The invention relates to a method for preparing an organic acid by electrolyzing an organic acid salt on the basis of a chlor-alkali perfluor ion exchange membrane. According to the method, an electrolytic bath which is equipped with a perfluor ion exchange membrane between electrodes and is mainly composed of an anode chamber, an anode, the perfluor ion exchange membrane, a cathode and a cathode chamber is adopted. The method comprises the following steps: respectively supplying an anode solution and a cathode solution to the anode chamber and the cathode chamber of the electrolytic bath and performing electrochemical ion exchange, wherein the anode solution is an aqueous solution of the organic acid salt and the cathode solution is an alkali solution corresponding to cations in the organic acid salt; applying a direct current to the electrolytic bath so as to perform constant current electrolysis, and combining the anions in the organic acid salt solution enriched in the anode chamber with hydrogen ions generated by the anode chamber, thereby generating the organic acid; and collecting discharged solution containing the organic acid enriched in the anode chamber, concentrating and crystallizing, thereby obtaining the high-purity organic acid. The method has the advantages of simple process, easiness in industrial amplification, high current efficiency, and the like, and can realize the industrial preparation for the high-purity organic acid.
Owner:SHANDONG DONGYUE POLYMER MATERIAL
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