2 results about "Diphenic acid" patented technology

The application provides a fluorescent metal organic framework material, a preparation method thereof and a detection method of magnetic substance content in a secondary battery negative electrode material, and belongs to the technical field of metal organic framework materials. The chemical formula of the fluorescent metal organic framework material is Ln2L3xH2O, wherein the inorganic metal center Ln is at least one of lanthanide metals, the organic ligand L has a diphenic acid structure, and x is 0-3. The fluorescent metal organic framework material has specific response to Fe 3+ and Cr 3+ magnetic substances, and exhibits the characteristics of rapidness, high selectivity and high sensitivity, and can detect the magnetic substances through an ultraviolet fluorescence (UV-vis) method.

The present application relates to the field of catalyst, especially to a MOFs catalyst and its preparation method and application.The method comprises: taking an aluminum-based MOF as a carrier, loading noble metal through an impregnation reduction method, and then performing gas phase reduction; wherein the aluminum-based MOF is synthesized by a hydrothermal method with a precursor and an organic ligand as raw materials, the metal precursor is an aluminum salt or a hydrated aluminum salt, and the organic ligand is selected from one or more of square acid, terephthalic acid, 2-fluoroterephthalic acid, diphenic acid, bipyridine, bipyridine dicarboxylic acid, trimesic acid, pyromellitic acid, and mellitic acid; the noble metal includes a Pd salt.The present application can prepare stable aluminum-based MOFs, obtain a strong interaction catalyst of noble metal and aluminum-based MOFs, the MOFs catalyst has stable properties, excellent performance, good morphology, high activity, and good selectivity for double bonds, and the MOFs catalyst can be recovered by centrifugation and reused multiple times.