The invention discloses a preparation method of a high-activity anti-
sulfur-poisoning
palladium carbon catalyst. The preparation method includes the following steps: step 1, adding
activated carbon into
hydrochloric acid for cooking, performing filtering, adding solids obtained by
filtration into
nitric acid for cooking, and performing filtering and washing to obtain the acid-treated
activated carbon; step 2, adding the acid-treated
activated carbon into a modifier solution, and stirring the solution to obtain paste; step 3, adding the paste into an assistant
metal salt solution, and stirringthe solution to obtain an activated carbon solution loaded with assistants; step 4, adding the activated carbon solution loaded with the assistants into a
palladium chloride solution, adjusting the pH, stirring the solution to obtain a
palladium suspension; step 5, reducing and filtering the palladium suspension, washing solids obtained by
filtration, and centrifuging and spin-
drying the solids toobtain the high-activity anti-
sulfur-poisoning palladium carbon catalyst. The preparation method has the advantages that
metal on the carrier surface of the obtained palladium carbon catalyst is highly dispersed, and high catalytic activity and anti-
sulfur stability in hydrogenation of nitrobenzyl
aniline and ortho-nitrotoluene are achieved.