The invention relates to the technical field of crossing of
material chemistry and water
electrolysis oxygen evolution, in particular to a method for preparing a
yolk shell structure high-entropy
phosphide FeCoNiCrMn-P catalyst through a low-temperature phosphating method. The method comprises the following steps: dissolving a plurality of nitrates in isopropanol and a glycerin
solvent to react to obtain high-entropy glycerate; carrying out
hydrothermal reaction on the reacted high-entropy glycerate to generate a high-entropy
hydroxide; the high-entropy
hydroxide and a
phosphorus source are subjected to a low-temperature phosphating reaction to generate the high-entropy
phosphide catalyst. According to the invention, the reactant FeCoNiCrMn-P with a graded egg
yolk shell structure not only exposes more active sites and provides abundant
mass transfer channels, but also provides a uniform environment for
heterogeneous catalysis, so that OER is promoted. In addition, the shell layer can also play a role of a protective layer, prevents the
active components from deforming and dissolving in the catalytic process, and enhances the stability of the
active components. When the
current density is 10 mA cm <-2 >, the FeCoNiCrMn-P2 has the best OER performance, and the
overpotential of the FeCoNiCrMn-P2 is 329 mV, so that the FeCoNiCrMn-P2 has high practical application value.